[Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br

Base Information

Chemical Name:[Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br
CAS No.:362598-03-6
Molecular Formula:Br*C₄₉H₄₂NP₂Ru
Molecular Weight:887.801
Hs Code.:

Synonyms:[Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br

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Chemical Property of [Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br

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Technology Process of [Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br

There total 1 articles about [Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 55272-32-7
[Ru(η5-Cp)(triphenylphosphine)2(CN)]

: 100-39-0
benzyl bromide

: 362598-03-6
[Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br

Guidance literature:: In chloroform; (N2); using Schlenk techniques; dissolving of RuCp(PPh3)2(CN) in CHCl3 at room temp.; addn. of BrCH2C6H5 via syringe; reflux for 2 days; removal of volatiles in vac., addn. of CH2Cl2 under N2; addn. of this soln. to vigorously stirred Et2O; pptn., filtration, washing with ether; elem. anal.;
DOI:10.1021/om049528t

Reference yield: 91.0%

: 362598-03-6
[Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br

: 67-64-1
acetone

: 362598-15-0
[Ru(η5-Cp)(triphenylphosphine)2(C3HNO(Ph)Me2)]

Guidance literature:: With (n-Bu)4NOH; In acetone; (N2); using Schlenk techniques; addn. of (n-Bu)4NOH to soln. of (Ru(PPh3)2(Cp)(CNCH2Ph))Br in acetone at room temp.; stirring for 5 min; removal of solvent under vac., extn. with hexane, filtration, removal ofsolvent under vac., elem. anal.;
DOI:10.1021/om049528t

Reference yield: 83.0%

: 12093-10-6
ferrocenecarboxaldehyde

: 362598-03-6
[Ru(η5-Cp)(triphenylphosphine)2(CNCH2C6H5)]Br

: [Ru(η5-Cp)(triphenylphosphine)2(C3H2NO(Ph)(ferrocenyl))]

Guidance literature:: With (n-Bu)4NOH; In dichloromethane; (N2); using Schlenk techniques; addn. of excess ferrocenecarboxaldehyde and (n-Bu)4NOH to soln. of (Ru(PPh3)2(Cp)(CNCH2Ph))Br in CH2Cl2; reflux for 90 min; removal of solvent under vac., extn. with hexane, filtration, removal ofsolvent under vac., elem. anal.;
DOI:10.1021/om049528t