2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

Base Information

Chemical Name:2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane
CAS No.:820217-04-7
Molecular Formula:C₅₈H₉₉NS₂Si₆Sn
Molecular Weight:1161.79
Hs Code.:

Synonyms:2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

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Chemical Property of 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

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Technology Process of 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

There total 6 articles about 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 176763-10-3
5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

: 103-72-0
phenyl isothiocyanate

: 820217-04-7
2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

Guidance literature:: With PPh₃; In hexane; byproducts: triphenylphosphine sulfide; (Ar); hexane added to a mixt. of Sn compd. and PPh3, refluxed for 70 min, cooled, treated with phenyl isothiocyanate at ambient temp.; evapd., subjected to HPLC, recrystd. (CH2Cl2/MeCN/EtOH); elem. anal.;
DOI:10.1021/ja048453h

Reference yield:

: 97443-80-6
(2-bromobenzene-1,3,5-triyl)tricyclohexane

: 820217-04-7
2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

Guidance literature:: Multi-step reaction with 5 steps

1: t-BuLi; Mg; I₂ / pentane; tetrahydrofuran

2: LiAlH₄ / tetrahydrofuran

3: diethyl ether

4: lithium naphthalenide / tetrahydrofuran

5: PPh₃ / hexane

With t-BuLi; Mg; I₂; LiAlH₄; lithium naphthalenide; PPh₃; In tetrahydrofuran; diethyl ether; hexane; pentane;
DOI:10.1021/ja048453h

Reference yield:

: 820217-08-1
dichloro(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane

: 820217-04-7
2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄ / tetrahydrofuran

2: diethyl ether

3: lithium naphthalenide / tetrahydrofuran

4: PPh₃ / hexane

With LiAlH₄; lithium naphthalenide; PPh₃; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/ja048453h