Silane, [[2-[dichloro(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-

Base Information

• Chemical Name: Silane, [[2-[dichloro(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-
• CAS No.: 820217-08-1
• Molecular Formula: C51H94Cl2Si6Sn
• Molecular Weight: 1065.41000
• Mol file: 820217-08-1.mol

Synonyms:

Chemical Property of Silane, [[2-[dichloro(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-

Chemical Property:

• PSA: 0.00000
• LogP: 17.66540

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, [[2-[dichloro(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-

There total 1 articles about Silane, [[2-[dichloro(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

tin(IV) chloride (7646-78-8) + 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene (115160-05-9) + (2-bromobenzene-1,3,5-triyl)tricyclohexane (97443-80-6) → dichloro(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-08-1)

Guidance literature:

With t-BuLi; Mg; I₂; In tetrahydrofuran; pentane; (Ar); t-BuLi/pentane added to a soln. of (((CH3)3Si)2CH)3C6H2Br/THF at -65°C, stirred for 30 min at the same temp., SnCl4 added at -65°C, warmed gradually to room temp., solvent-removed, pptd. (hexane),dissolved in THF,; a soln. of a Mg compd. (prepd. from BrC6H2(C6H11)3, Mg and I2 in THF under reflux for hours) added at room temp., refluxed for 16 h; cooled to room temp., evapd., pptd. (hexane), subjected to wet-column chromy. (hexane), HPLC; obtained crude;

DOI:10.1021/ja048453h

Reference yield: 74.0%

dichloro(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-08-1) → (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-25-2)

Guidance literature:

With LiAlH₄; In tetrahydrofuran; (Ar); Sn compd. added to a suspn. of LiAlH4, stirred for 2 h; treated with EtOAc and H2O, evapd., subjected to dry-column chromy.;

DOI:10.1021/ja048453h

Reference yield:

dichloro(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-08-1) → 5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetraselenastannolane (198023-01-7)

Guidance literature:

Multi-step reaction with 3 steps

1: LiAlH₄ / tetrahydrofuran

2: diethyl ether

3: lithium naphthalenide / tetrahydrofuran

With LiAlH₄; lithium naphthalenide; In tetrahydrofuran; diethyl ether;

DOI:10.1021/ja048453h

upstream raw materials:

tin(IV) chloride

1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene

(2-bromobenzene-1,3,5-triyl)tricyclohexane

Downstream raw materials:

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane

2,4,6-tris[bis(trimethylsilyl)methyl]phenyl(2,4,6-tricyclohexylphenyl)Sn=Se

5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetraselenastannolane

2,4,6-tris[bis(trimethylsilyl)methyl]phenyl(2,4,6-tricyclohexylphenyl)Sn=S