5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

Base Information

Chemical Name:5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane
CAS No.:176763-10-3
Molecular Formula:C₅₁H₉₄S₄Si₆Sn
Molecular Weight:1122.79
Hs Code.:

Synonyms:5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

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Chemical Property of 5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

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Technology Process of 5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

There total 5 articles about 5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 10544-50-0
sulfur

: 820217-14-9
dibromo(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane

: 176763-10-3
5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

Guidance literature:: With lithium naphthalenide; In tetrahydrofuran; (Ar); lithium naphthalenide in THF added a THF soln. of Sn compd. at -70°C, stirred for 30 min at this temp., treated with S8 at -70°C, stirred for 3 h while warmed to room temp.; solvent-removed, subjected to chromy. (Florisil/CH2Cl2), HPLC, recrystd.(CH2Cl2/MeCN); elem. anal.;
DOI:10.1021/ja048453h

Reference yield:

: 97443-80-6
(2-bromobenzene-1,3,5-triyl)tricyclohexane

: 176763-10-3
5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

Guidance literature:: Multi-step reaction with 4 steps

1: t-BuLi; Mg; I₂ / pentane; tetrahydrofuran

2: LiAlH₄ / tetrahydrofuran

3: diethyl ether

4: lithium naphthalenide / tetrahydrofuran

With t-BuLi; Mg; I₂; LiAlH₄; lithium naphthalenide; In tetrahydrofuran; diethyl ether; pentane;
DOI:10.1021/ja048453h

Reference yield:

: 820217-08-1
dichloro(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane

: 176763-10-3
5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetrathiastannolane

Guidance literature:: Multi-step reaction with 3 steps

1: LiAlH₄ / tetrahydrofuran

2: diethyl ether

3: lithium naphthalenide / tetrahydrofuran

With LiAlH₄; lithium naphthalenide; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ja048453h