phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside
CAS No.:1447935-02-5
Molecular Formula:C₄₀H₃₉NO₇S
Molecular Weight:677.818
Hs Code.:

Synonyms:phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Suppliers and Price of phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

There total 5 articles about phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 152871-96-0
phenyl 1-deoxy-2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

: 3958-60-9
2-nitrophenylmethyl bromide

: 1447935-02-5
phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Guidance literature:: phenyl 1-deoxy-2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside; With potassium cyanide; In methanol; for 4h;

With sodium hydride; In acetonitrile; mineral oil; at 0 ℃; for 0.5h;

2-nitrophenylmethyl bromide; In acetonitrile; mineral oil; at 0 - 20 ℃;
DOI:10.1002/ejoc.201300123

Reference yield:

: 100-39-0
benzyl bromide

: 1447935-02-5
phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium cyanide / methanol / 4 h

1.2: 0.5 h / 0 °C

1.3: 0 - 20 °C

2.1: boron trifluoride diethyl etherate / dichloromethane / 1 h / -45 - -25 °C

3.1: boron trifluoride diethyl etherate / dichloromethane / -45 - 20 °C / Sonication

4.1: potassium cyanide / methanol / 4 h

4.2: 0.5 h / 0 °C

4.3: 0 - 20 °C

With potassium cyanide; boron trifluoride diethyl etherate; In methanol; dichloromethane;
DOI:10.1002/ejoc.201300123

Reference yield:

: 65827-55-6,68567-54-4,77790-45-5,77790-46-6,81969-44-0,99630-89-4,125135-30-0,137567-77-2,55628-56-3
1,2-di-O-acetyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside

: 1447935-02-5
phenyl 2-O-(o-nitrobenzyl)-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: boron trifluoride diethyl etherate / dichloromethane / -45 - 20 °C / Sonication

2.1: potassium cyanide / methanol / 4 h

2.2: 0.5 h / 0 °C

2.3: 0 - 20 °C

With potassium cyanide; boron trifluoride diethyl etherate; In methanol; dichloromethane;
DOI:10.1002/ejoc.201300123