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2-(Allyldimethylsilyl)pyridine

Base Information Edit
  • Chemical Name:2-(Allyldimethylsilyl)pyridine
  • CAS No.:118722-54-6
  • Molecular Formula:C10H15 N Si
  • Molecular Weight:177.321
  • Hs Code.:
  • European Community (EC) Number:623-238-2
  • DSSTox Substance ID:DTXSID80459017
  • Nikkaji Number:J1.816.081A
  • Mol file:118722-54-6.mol
2-(Allyldimethylsilyl)pyridine

Synonyms:2-(Allyldimethylsilyl)pyridine;118722-54-6;dimethyl-prop-2-enyl-pyridin-2-ylsilane;(2-PYRIDYL)ALLYLDIMETHYLSILANE;2-(ALLYLDIMETHYLSILYL)PYRIDINE, 90per cent;SCHEMBL2328923;DTXSID80459017;WIRIPVDRZYVTCG-UHFFFAOYSA-N;AKOS025394194;2-(ALLYLDIMETHYLSILYL)PYRIDINE, 90%;2-[DIMETHYL(PROP-2-EN-1-YL)SILYL]PYRIDINE

Suppliers and Price of 2-(Allyldimethylsilyl)pyridine
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Sigma-Aldrich
  • 2-(Allyldimethylsilyl)pyridine 90%
  • 5g
  • $ 461.00
  • Sigma-Aldrich
  • 2-(Allyldimethylsilyl)pyridine 90%
  • 1g
  • $ 144.00
  • American Custom Chemicals Corporation
  • 2-(ALLYLDIMETHYLSILYL)PYRIDINE 95.00%
  • 1G
  • $ 737.35
  • AK Scientific
  • 2-(Allyldimethylsilyl)pyridine
  • 5g
  • $ 750.00
  • AK Scientific
  • 2-(Allyldimethylsilyl)pyridine
  • 1g
  • $ 234.00
Total 15 raw suppliers
Chemical Property of 2-(Allyldimethylsilyl)pyridine Edit
Chemical Property:
  • Vapor Pressure:0.14mmHg at 25°C 
  • Refractive Index:n20/D 1.5046 
  • Boiling Point:223.9°C at 760 mmHg 
  • Flash Point:71 °C 
  • PSA:12.89000 
  • Density:0.913 g/mL at 25 °C 
  • LogP:2.18300 
  • Storage Temp.:2-8°C 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:1
  • Rotatable Bond Count:3
  • Exact Mass:177.097376017
  • Heavy Atom Count:12
  • Complexity:154
Purity/Quality:

98% *data from raw suppliers

2-(Allyldimethylsilyl)pyridine 90% *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes:Xi 
  • Statements: 36/37/38 
  • Safety Statements: 26 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:C[Si](C)(CC=C)C1=CC=CC=N1
  • Uses 2-(Allyldimethylsilyl)pyridine can be used as a pyridyl transfer reagent to prepare substituted pyridine derivatives by reacting with various aryl iodides in the presence of a palladium catalyst and silver(I) oxide activator. It can also be utilized as a coupling reagent in the allylation of carbonyl compounds using a copper catalyst.
Technology Process of 2-(Allyldimethylsilyl)pyridine

There total 1 articles about 2-(Allyldimethylsilyl)pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
2-bromo-pyridine; With n-butyllithium; In hexane; at -78 ℃; for 1h; Inert atmosphere; Schlenk technique;
Allylchlorodimethylsilane; In hexane; at -78 - 20 ℃; for 18h; Inert atmosphere; Schlenk technique;
DOI:10.1002/chem.201505092
Guidance literature:
With copper(l) iodide; cesium fluoride; In tetrahydrofuran; at 20 ℃; for 2h;
DOI:10.1021/ol051925s
Guidance literature:
With silver(I) acetate; In toluene; at 100 ℃; for 15h; Further Variations:; Reagents; Temperatures; Solvents; Product distribution;
DOI:10.1246/cl.2002.1084
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