3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose

Base Information

Chemical Name:3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose
CAS No.:161045-46-1
Molecular Formula:C₂₀H₂₆O₉S
Molecular Weight:442.487
Hs Code.:

Synonyms:3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose

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Chemical Property of 3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose

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Technology Process of 3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose

There total 3 articles about 3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 124-63-0
methanesulfonyl chloride

: Benzoic acid (R)-2-((3aR,5R,6S,6aR)-6-allyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-hydroxy-ethyl ester

: 161045-46-1
3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose

Guidance literature:: With pyridine; In dichloromethane; at -20 - 0 ℃; Yield given;
DOI:10.1246/cl.1994.2119

Reference yield:

: 582-52-5
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 161045-46-1
3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 4 steps

1: 188 g / NaH / dimethylformamide / 3.5 h / 0 °C

2: 175 g / acetic acid; H₂O / 16 h / 60 °C

3: CH₂Cl₂; pyridine / 1 h / -15 °C

4: 179 g / CH₂Cl₂; pyridine / 20 h / -15 - 20 °C

With sodium hydride; In pyridine; dichloromethane; water; acetic acid; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)00642-1

Reference yield:

: 91882-92-7
3-O-allyl-1,2-O-isopropylidene-α-D-glucofuranose

: 161045-46-1
3-O-allyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂; pyridine / 1 h / -15 °C

2: 179 g / CH₂Cl₂; pyridine / 20 h / -15 - 20 °C

In pyridine; dichloromethane;
DOI:10.1016/S0040-4020(01)00642-1