[para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

Base Information

Chemical Name:[para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl
CAS No.:548464-47-7
Molecular Formula:C₁₈H₂₃ClN₂Pd
Molecular Weight:409.267
Hs Code.:

[para-Ph-C<sub>6</sub>H<sub>2</sub>(CH<sub>2</sub>NMe<sub>2</sub>)2-2,6-pincer palladium(II)]Cl

Synonyms:[para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

Suppliers and Price of [para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

There total 2 articles about [para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 184651-94-3
C₆H₅C₆H₃(CH₂N(CH₃)2)2

: 548464-47-7
[para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

Guidance literature:: With nBuLi; In diethyl ether; hexane; nBuLi added to soln. of org. compd. in hexane at -80°C, temp. allowed to rise to room temp., stirred for 4 h, this soln. added to suspn. of Pd compd. in Et2O at room temp., stirred for 3 h; solvents evapd., extd. with CH2Cl2, org. layer filtered, concd., pptd. with Et2O, dried in vac., dissolved in CH2Cl2, Et2O diffunded, elem. anal.;
DOI:10.1002/ejic.200390113

Reference yield: 62.0%

: 27199-13-9,14873-91-7,55528-77-3
bis(diethyl sulfide)palladium dichloride

: 184651-94-3
C₆H₅C₆H₃(CH₂N(CH₃)2)2

: 548464-47-7
[para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

Guidance literature:: With n-butyl lithium; In hexane; pentane; under N2; n-BuLi/hexane added to soln. of ligand in pentane at -78°C, stirred at -78°C for 0.5 h, warmed overnight, pentane replaced by Et2O, cooled to -78°C, Pd complex added, stirred at -78°C for 1 h, warmed overnight; soln. evapd., residue dissolved in CH2Cl2, washed with water and brine, dried over MgSO4, filtered through Celite, hexane added to filtrate, slow evapn.;
DOI:10.1021/om801200c

Reference yield: 93.0%

: 14104-20-2
silver tetrafluoroborate

: 548464-47-7
[para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II)]Cl

: 7732-18-5
water

: 548464-57-9
[(para-Ph-C₆H₂(CH₂NMe₂)2-2,6-pincer palladium(II))OH₂]BF₄

Guidance literature:: In acetone; AgBF4 in wet acetone added to soln. of Pd complex, stirred at room temp.for 1 h; filtered, concd., pptd. with Et2O;
DOI:10.1002/ejic.200390113