(4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate

Base Information

• Chemical Name: (4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate
• CAS No.: 179108-72-6
• Molecular Formula: C₂₆H₃₄ClNO₂Si
• Molecular Weight: 456.1
• Mol file: 179108-72-6.mol

Synonyms:(4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate

Chemical Property of (4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate

There total 3 articles about (4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

dimethylmonochlorosilane (1066-35-9) + (4'-cyanobiphenyl-4-yl) undec-10-enoate (119081-67-3) → (4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate (179108-72-6)

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane; at 60 ℃; for 9h;

DOI:10.1023/A:1025609613210

Reference yield:

undec-10-enoyl chloride (38460-95-6) → (4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate (179108-72-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / triethylamine / tetrahydrofuran

2: 95 percent / Carsted catalyst PCO₇₂ / 9 h / 60 °C

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane; triethylamine; In tetrahydrofuran;

DOI:10.1023/A:1025609613210

Reference yield:

4-Cyano-4'-hydroxybiphenyl (19812-93-2) → (4'-cyanobiphenyl-4-yl) 11-(dimethylchlorosilyl)undecanoate (179108-72-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / triethylamine / tetrahydrofuran

2: 95 percent / Carsted catalyst PCO₇₂ / 9 h / 60 °C

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane; triethylamine; In tetrahydrofuran;

DOI:10.1023/A:1025609613210

upstream raw materials:

dimethylmonochlorosilane

(4'-cyanobiphenyl-4-yl) undec-10-enoate

undec-10-enoyl chloride

4-Cyano-4'-hydroxybiphenyl