(1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane

Base Information

• Chemical Name: (1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane
• CAS No.: 1034137-96-6
• Molecular Formula: C₂₂H₃₀Si₂
• Molecular Weight: 350.651
• Mol file: 1034137-96-6.mol

Synonyms:(1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane

Chemical Property of (1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane

There total 1 articles about (1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyldimethylsilyl chloride (768-33-2) + methanesulfonic acid 1-phenethyl-3-trimethylsilanylprop-2-ynyl ester (777060-75-0) → (1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane (1034137-96-6)

Guidance literature:

phenyldimethylsilyl chloride; With lithium; In tetrahydrofuran; at 0 ℃; for 6h; Inert atmosphere;

With copper(I) cyanide*lithium chloride; In tetrahydrofuran; at -78 ℃; for 0.25h; Inert atmosphere;

methanesulfonic acid 1-phenethyl-3-trimethylsilanylprop-2-ynyl ester; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1039/b803888k

Reference yield: 70.0%

(1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane (1034137-96-6) → (3-fluoro-5-phenyl-pent-1-ynyl)dimethyl(phenyl)silane (1034137-98-8)

Guidance literature:

(1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane; With 1-chloromethyl-4-fluoro-1,4-diazobicyclo[2.2.2]octane bis(tetrafluoroborate); In acetonitrile; at 20 ℃; for 24h;

Inert atmosphere;

DOI:10.1039/b803888k

upstream raw materials:

phenyldimethylsilyl chloride

methanesulfonic acid 1-phenethyl-3-trimethylsilanylprop-2-ynyl ester

Downstream raw materials:

(3-fluoro-5-phenyl-pent-1-ynyl)dimethyl(phenyl)silane