777060-75-0

Upstream product

• 1066-54-2 trimethylsilylacetylene 
• 104-53-0 3-phenyl-propionaldehyde 
• 140149-77-5 5-phenyl-1-trimethylsilylpent-1-yn-3-ol 
• 124-63-0 methanesulfonyl chloride 

Downstream Products

• 1034137-96-6 (1-(dimethyl(phenyl)silyl)-5-phenylpenta-1,2-dienyl)trimethylsilane 
• 1310824-77-1 C₁₄H₁₉ClSi 
• 1391157-58-6 3-cyclohexyl-5,5-dimethyl-2-(trimethylsilyl)hexa-1,3(Z)-dien-1-one 
• 1391157-44-0 methyl 6-phenyl-2-(trimethylsilyl)hexa-2,3-dienoate 
• 777060-80-7 N-(4-hydroxy-1-phenethyl-4-phenylbut-2-ynyl)-benzamide 
• 777060-79-4 N-(1-phenethylprop-2-ynyl)-benzamide 
• 777060-77-2 1-phenethyl-3-trimethylsilanylprop-2-ynylamine 
• 777060-78-3 1-phenethylprop-2-ynylamine 
• 916155-47-0 (2,2-dimethyl-7-phenylhepta-3,4-dien-3-yl)trimethylsilane 
• 916155-46-9 trimethyl(6-phenylhexa-2,3-dien-2-yl)silane 
• 152710-28-6 1-phenyl-5-trimethylsilyl-3,4-nonadiene 
• 850452-33-4 1-[5,6-bis(trimethylsilyl)hexa-3,4-dienyl]benzene 
• 777060-76-1 (3-azido-5-phenylpent-1-ynyl)-trimethylsilane 

Relevant academic research and scientific papers

Iron-catalyzed unexpected easy access to stereodefined trimethylsilyl vinyl ketenes

Stereodefined trimethylsilyl vinyl ketenes with polysubstitution have been synthesized highly regio- and stereoselectively via an iron-catalyzed reaction of 2-trimethylsilyl-2,3-allenoates with Grignard reagents in good to excellent yields. The reaction w

Spirodiepoxide-based cascades: Direct access to diverse motifs

Allene epoxide formation/opening reaction sequences enabled direct access to diverse products. Described here are a single flask procedure for allene preparation and allene oxidation/derivatization reactions that give, among others, diendiol, diyndiol, α′-hydroxy-γ-enone, dihydrofuranone, butenolide, and δ-lactone products.

Stereospecific anti SE2′ fluorination of allenylsilanes: Synthesis of enantioenriched propargylic fluorides

The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereosp

Synthesis of propargylic fluorides from allenylsilanes

Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate. The Royal Society of Chemistry 2006.

Electrophilic fluorodesilylation of allenylmethylsilanes: A novel entry to 2-fluoro-1,3-dienes

(Chemical Equation Presented) Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows

A practical method for oxazole synthesis by cycloisomerization of propargyl amides

(Chemical Equation Presented) 2,5-Disubstituted and 2,4,5-trisubstituted oxazol-5-yl carbonyl compounds were prepared in good yields by a mild SiO 2-mediated cycloisomerization of propargyl amides.