2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone

Base Information

• Chemical Name: 2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone
• CAS No.: 164401-09-6
• Molecular Formula: C₃₃H₅₀OSSn
• Molecular Weight: 613.535
• Mol file: 164401-09-6.mol

Synonyms:2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone

Chemical Property of 2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone

There total 1 articles about 2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3-phenyl-1,1-bis(phenylthio)-1-tributylstannylpropane (142073-43-6) + 1-(Trimethylsilyloxy)cyclohexene (6651-36-1) + tin(IV) chloride (7646-78-8) → 2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone (164401-09-6)

Guidance literature:

In dichloromethane; to a CH2Cl2 solution of the α-tributylstannylthioacetal and the silyl-compound was added SnCl4 in CH2Cl2 at -78°C; stirring for 4 h; addition of water; extraction with CH2Cl2; dried (Na2SO4); condensed under reduced pressure; residue was purified by silica-gel chromatography (hexane:AcOEt = 98:2); IR, NMR;

DOI:10.1246/cl.1992.819

Reference yield: 85.0%

2-(3-phenyl-1-phenylthio-1-tributylstannyl)propylcyclohexanone (164401-09-6) → (Z)-2-(3-phenyl-1-tributylstannylpropylidene)cyclohexanone (142073-61-8)

Guidance literature:

With potassium hydride; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; byproducts: C6H5SH; 5 equivalents KH; 3 h; 0°C; IR, NMR;

DOI:10.1246/cl.1992.819

upstream raw materials:

3-phenyl-1,1-bis(phenylthio)-1-tributylstannylpropane

1-(Trimethylsilyloxy)cyclohexene

tin(IV) chloride

Downstream raw materials:

(Z)-2-(3-phenyl-1-tributylstannylpropylidene)cyclohexanone