[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

Base Information

Chemical Name:[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride
CAS No.:124643-10-3
Molecular Formula:C₂₂H₁₇Cl₃N₃Os
Molecular Weight:619.956
Hs Code.:

Synonyms:[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

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Chemical Property of [4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

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Technology Process of [4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

There total 1 articles about [4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: diammonium hexachloroosmate(IV)

: 89972-77-0
4'-(4-methylphenyl)-2,2':6',2-terpyridine

: 124643-10-3
[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

Guidance literature:: In N,N-dimethyl-formamide; for 1h; Reflux;
DOI:10.1021/ic400385b

Reference yield: 69.6%

: 4'-[4-N-(2,4,6-triphenylpyridinio)phenyl]-2,2':6',2''-terpyridine(0.1HSO₄, 0.9OAc)

: ammonium hexafluorophosphate

: 124643-10-3
[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

: 7732-18-5
water

: Os((C₅H₄N)2C₅H₂NC₆H₄C₅H₂N(C₆H₅)3)CH₃C₆H₄C₅H₂N(C₅H₄N)2⁽³⁺⁾*3PF₆^(1-)*3H₂O=C₆₆H₅₄N₇OsP₃F₁₈O₃

Guidance literature:: With sodium ascorbate; In ethylene glycol; mixt. of Os-complex, ligand, sodium ascorbate and 1,2-ethanediol was heated to 110°C for 14 h under Ar, cooled to room temp., EtOH, H2O and NH4PF6 were added, stirred; filtered, washed with H2O, EtOH, Et2O, column chromy. on alumina with CH2Cl2/acetone, acetone with MeCN, soln. of NH4PF6 in MeCN, pptd. with EtOH, recrystd. by slow vapor diffusion of Et2O in MeCN; elem. anal.;
DOI:10.1021/ja011069p

Reference yield: 66.0%

: 7791-07-3
sodium perchlorate monohydrate

: 124643-10-3
[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

: [(phen)₂Ru(4′-[4-(4,5-di-pyridin-2-yl-1H-imidazol-2-yl)-phenyl]-[2,2′;6′,2″]terpyridine)](ClO₄)₂

: C₈₀H₅₆N₁₄OsRu⁽⁴⁺⁾*4ClO₄^(1-)*H₂O

Guidance literature:: [4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride; [(phen)₂Ru(4′-[4-(4,5-di-pyridin-2-yl-1H-imidazol-2-yl)-phenyl]-[2,2′;6′,2″]terpyridine)](ClO₄)₂; In ethylene glycol; for 6h; Inert atmosphere; Reflux;

sodium perchlorate monohydrate; In water; at 20 ℃;
DOI:10.1039/c7dt02192e