5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine

Base Information

• Chemical Name: 5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine
• CAS No.: 115083-91-5
• Molecular Formula: C₅₈H₄₄N₄O₂
• Molecular Weight: 829.013
• Mol file: 115083-91-5.mol

Synonyms:5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine

Chemical Property of 5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine

There total 5 articles about 5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

α-naphthol (90-15-3) + 5-(4-bromotetramethyleneoxyphenyl)-10,15,20-triphenylporphine (102202-48-2) → 5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine (115083-91-5)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 24h;

DOI:10.1007/BF00486911

Reference yield: 6.9%

pyrrole (109-97-7,30604-81-0) + 4-[4-(naphthalen-1-yloxy)butoxy]benzaldehyde + benzaldehyde (100-52-7) → 5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine (115083-91-5)

Guidance literature:

pyrrole; 4-[4-(naphthalen-1-yloxy)butoxy]benzaldehyde; benzaldehyde; With boron trifluoride diethyl etherate; In chloroform; at 20 ℃; for 48h; Inert atmosphere;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; at 20 ℃; for 30h; Inert atmosphere;

DOI:10.1007/s10847-017-0724-6

Reference yield:

5-(4'-hydroxyphenyl)-10,15,20-triphenylporphyrin (87345-22-0) → 5-<4-(1-naphtyloxy)tetramethyleneoxyphenyl>-10,15,20-triphenylporphine (115083-91-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 45 percent / anhydrous potassium carbonate / dimethylformamide / 24 h / 20 °C

2: 15 percent / anhydrous potassium carbonate / dimethylformamide / 24 h / 20 °C

With potassium carbonate; In N,N-dimethyl-formamide;

DOI:10.1007/BF00486911

upstream raw materials:

α-naphthol

5-(4-bromotetramethyleneoxyphenyl)-10,15,20-triphenylporphine

5-(4'-hydroxyphenyl)-10,15,20-triphenylporphyrin

pyrrole