[((η5-C5(CH3)5)Rh)2(μ-HNTs)2]

Base Information

Chemical Name:[((η5-C5(CH3)5)Rh)2(μ-HNTs)2]
CAS No.:1140949-74-1
Molecular Formula:C₃₄H₄₆N₂O₄Rh₂S₂
Molecular Weight:816.693
Hs Code.:

Synonyms:[((η5-C5(CH3)5)Rh)2(μ-HNTs)2]

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Chemical Property of [((η5-C5(CH3)5)Rh)2(μ-HNTs)2]

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Technology Process of [((η5-C5(CH3)5)Rh)2(μ-HNTs)2]

There total 4 articles about [((η5-C5(CH3)5)Rh)2(μ-HNTs)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1075256-79-9
[((η5-C5(CH3)5)Rh)(μ-NTs)]2

: 1333-74-0
hydrogen

: 1140949-74-1
[((η5-C5(CH3)5)Rh)2(μ-HNTs)2]

Guidance literature:: In dichloromethane; 1 atm H2 gas was introduced to the Schlenk tube with soln. of complex inCH2Cl2, the mixt. was stirred at room temp. for 24 h; the solvent was removed in vac., the solid was extd. with toluene, hexane was added, concd., cooled at 2°C; elem. anal.;

Reference yield: 76.0%

: 1075256-79-9
[((η5-C5(CH3)5)Rh)(μ-NTs)]2

: 67-63-0,8013-70-5
isopropyl alcohol

: 1140949-74-1
[((η5-C5(CH3)5)Rh)2(μ-HNTs)2]

Guidance literature:: In dichloromethane; byproducts: acetone; (Ar, Schlenk) to a soln. of complex in CH2Cl2 was added 2-propanol, the mixt. was stirred for 16 h at room temp.; the solvent was removed in vac., the solid was extd. with toluene, hexane was added, concd., cooled at 2°C;

Reference yield: 57.0%

: 1140949-79-6
[((η5-C5(CH3)5)Rh)2(μ-HNTs)(μ-NTs)][OTf]

: 22560-16-3
lithium triethylborohydride

: 1140949-74-1
[((η5-C5(CH3)5)Rh)2(μ-HNTs)2]

Guidance literature:: In tetrahydrofuran; dichloromethane; (Ar, Schlenk) to a soln. of complex in CH2Cl2 was added a THF-soln. of LiBH(C2H5)3 at 0°C, the mixt. was slowly warmed to room temp. withstirring, 3 h; evapd. to dryness, the solid was extd. with toluene, hexane was added, cooled at 2°C;