(R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

Base Information

Chemical Name:(R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol
CAS No.:1353566-48-9
Molecular Formula:C₂₈H₅₀O₂Si
Molecular Weight:446.789
Hs Code.:

Synonyms:(R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

Suppliers and Price of (R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

Chemical Property:

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Technology Process of (R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

There total 6 articles about (R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 629-03-8
1 ,6-dibromohexane

: 1353566-48-9
(R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

Guidance literature:: Multi-step reaction with 5 steps

1.1: magnesium / tetrahydrofuran / Inert atmosphere

1.2: 16 h / -10 - 20 °C / Inert atmosphere

2.1: magnesium / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere

2.2: 18 h / 0 - 4 °C / Inert atmosphere

3.1: tert.-butyl lithium / diethyl ether; pentane / 0.5 h / -78 °C / Inert atmosphere

3.2: 0.17 h / -25 °C / Inert atmosphere

4.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

5.1: silica gel / diethyl ether; Petroleum ether / Inert atmosphere

With tert.-butyl lithium; silica gel; magnesium; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane; Petroleum ether; pentane;
DOI:10.1021/ol203185f

Reference yield:

: 1353566-53-6
(R)-3,3,8,8-tetraethyl-5-methyl-5-(2-methylene-12-phenyldodecyl)-4,7-dioxa-3,8-disiladecane

: 1353566-48-9
(R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

Guidance literature:: With silica gel; In diethyl ether; Petroleum ether; Inert atmosphere;
DOI:10.1021/ol203185f

Reference yield:

: 1353566-45-6
(11-bromododec-11-en-1-yl)benzene

: 1353566-48-9
(R)-2-methyl-4-methylene-14-phenyl-2-((triethylsilyl)oxy)tetradecan-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: tert.-butyl lithium / diethyl ether; pentane / 0.5 h / -78 °C / Inert atmosphere

1.2: 0.17 h / -25 °C / Inert atmosphere

2.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

3.1: silica gel / diethyl ether; Petroleum ether / Inert atmosphere

With tert.-butyl lithium; silica gel; triethylamine; In diethyl ether; dichloromethane; Petroleum ether; pentane;
DOI:10.1021/ol203185f