1H-Indene-1-carboxylicacid,3-amino-2,3-dihydro-,methylester,(1R,3S)-rel-

Base Information

Chemical Name:1H-Indene-1-carboxylicacid,3-amino-2,3-dihydro-,methylester,(1R,3S)-rel-
CAS No.:111634-91-4
Molecular Formula:C₁₁H₁₃NO₂
Molecular Weight:191.23
Hs Code.:
Mol file:111634-91-4.mol

Synonyms:1H-Indene-1-carboxylicacid, 3-amino-2,3-dihydro-, methyl ester, cis-

Suppliers and Price of 1H-Indene-1-carboxylicacid,3-amino-2,3-dihydro-,methylester,(1R,3S)-rel-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1H-Indene-1-carboxylicacid,3-amino-2,3-dihydro-,methylester,(1R,3S)-rel-

Chemical Property:

Boiling Point:295.8±40.0 °C(Predicted)
PKA:8.93±0.40(Predicted)
PSA：52.32000
Density:1.168±0.06 g/cm3(Predicted)
LogP:2.04700

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1H-Indene-1-carboxylicacid,3-amino-2,3-dihydro-,methylester,(1R,3S)-rel-

There total 5 articles about 1H-Indene-1-carboxylicacid,3-amino-2,3-dihydro-,methylester,(1R,3S)-rel- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 185122-64-9,111634-90-3,111634-92-5
Methyl 3-hydroxyimino-1-indanecarboxylate

: 111634-91-4,185122-65-0
Methyl (+/-)-cis-3-amino-1-indanecarboxylate

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; chloroform; for 19h; under 2585.7 Torr;
DOI:10.1021/jm00397a029

Reference yield: 55.0%

: 185122-64-9,111634-90-3,111634-92-5
Methyl 3-hydroxyimino-1-indanecarboxylate

: 111634-91-4,185122-65-0
Methyl (+/-)-cis-3-amino-1-indanecarboxylate

: 185122-65-0
Methyl (+/-)-trans-3-amino-1-indanecarboxylate

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; for 20h; under 2585.74 Torr;
DOI:10.1055/s-2001-10811

Reference yield:

: 29427-69-8
3-oxoindan-1-carboxylic acid

: 111634-91-4,185122-65-0
Methyl (+/-)-cis-3-amino-1-indanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 5.75 g / H₂SO₄ / 16 h / Heating

2: 91 percent / H₂NOH*HCl; NaOAc / aq. ethanol / 1 h / Heating

3: 55 percent / H₂ / 10 percent Pd/C / methanol / 20 h / 2585.74 Torr

With sulfuric acid; hydroxylamine hydrochloride; hydrogen; sodium acetate; palladium on activated charcoal; In methanol; ethanol;
DOI:10.1055/s-2001-10811