METHYL 3-HYDROXYIMINOINDAN-1-CARBOXYLATE

Base Information

Chemical Name:METHYL 3-HYDROXYIMINOINDAN-1-CARBOXYLATE
CAS No.:185122-64-9
Molecular Formula:C₁₁H₁₁NO₃
Molecular Weight:205.213
Hs Code.:
Mol file:185122-64-9.mol

Synonyms:METHYL 3-HYDROXYIMINOINDAN-1-CARBOXYLATE;1H-Indene-1-carboxylicacid,2,3-dihydro-3-(hydroxyimino)-,methylester(9CI)

Suppliers and Price of METHYL 3-HYDROXYIMINOINDAN-1-CARBOXYLATE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of METHYL 3-HYDROXYIMINOINDAN-1-CARBOXYLATE

Chemical Property:

Vapor Pressure:5.35E-05mmHg at 25°C
Refractive Index:1.602
Boiling Point:333.6°Cat760mmHg
Flash Point:155.6°C
PSA：58.89000
Density:1.3g/cm³
LogP:1.52520

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of METHYL 3-HYDROXYIMINOINDAN-1-CARBOXYLATE

There total 3 articles about METHYL 3-HYDROXYIMINOINDAN-1-CARBOXYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 29427-70-1
methyl 3-oxo-2,3-dihydro-1H-indene-1-carboxylate

: 185122-64-9,111634-90-3,111634-92-5
Methyl 3-hydroxyimino-1-indanecarboxylate

Guidance literature:: With hydroxylamine hydrochloride; sodium acetate; In ethanol; for 1h; Heating;
DOI:10.1021/jm00397a029

Reference yield:

: 29427-69-8
3-oxoindan-1-carboxylic acid

: 185122-64-9,111634-90-3,111634-92-5
Methyl 3-hydroxyimino-1-indanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 5.75 g / H₂SO₄ / 16 h / Heating

2: 91 percent / H₂NOH*HCl; NaOAc / aq. ethanol / 1 h / Heating

With sulfuric acid; hydroxylamine hydrochloride; sodium acetate; In ethanol;
DOI:10.1055/s-2001-10811

Reference yield:

: 1131-15-3,112489-85-7
2-phenylsuccinic anhydride

: 185122-64-9,111634-90-3,111634-92-5
Methyl 3-hydroxyimino-1-indanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: AlCl₃ / 1,2-dichloro-ethane / 0.67 h / 20 °C

2: 5.75 g / H₂SO₄ / 16 h / Heating

3: 91 percent / H₂NOH*HCl; NaOAc / aq. ethanol / 1 h / Heating

With aluminium trichloride; sulfuric acid; hydroxylamine hydrochloride; sodium acetate; In ethanol; 1,2-dichloro-ethane;
DOI:10.1055/s-2001-10811