[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine

Base Information

• Chemical Name: [(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine
• CAS No.: 135508-30-4
• Molecular Formula: C₂₆H₃₁NO₂Si
• Molecular Weight: 417.623

Synonyms:[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine

Chemical Property of [(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine

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Technology Process of [(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine

There total 2 articles about [(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-2-(O-tert-butyldiphenylsilyloxy)propanal (87696-33-1) + 4-methoxy-aniline (104-94-9) → [(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine (135508-30-4)

Guidance literature:

With magnesium sulfate; In dichloromethane; at 0 ℃; for 4h;

DOI:10.1021/jo00059a003

Reference yield:

(S)-2-(O-tert-butyldiphenylsilyloxy)propanal (87696-33-1) + 4-methoxy-aniline (104-94-9) → [(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(Z)-ylidene]-(4-methoxy-phenyl)-amine (135508-30-4)

Guidance literature:

DOI:10.1016/0040-4039(91)80701-7

Reference yield: 70.0%

Benzyloxyacetyl chloride (19810-31-2) + [(S)-2-(tert-Butyl-diphenyl-silanyloxy)-prop-(E)-ylidene]-(4-methoxy-phenyl)-amine (135508-30-4) → (3S,4S)-3-Benzyloxy-4-[(S)-1-(tert-butyl-diphenyl-silanyloxy)-ethyl]-1-(4-methoxy-phenyl)-azetidin-2-one (135508-38-2)

Guidance literature:

With triethylamine; In dichloromethane; -78 deg C to RT, 24 h;

DOI:10.1021/jo00059a003

upstream raw materials:

(S)-2-(O-tert-butyldiphenylsilyloxy)propanal

4-methoxy-aniline

Downstream raw materials:

(3S,4S)-4-[(S)-1-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methoxy-1-(4-methoxy-phenyl)-azetidin-2-one

(3R,4R)-4-[(S)-1-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methoxy-1-(4-methoxy-phenyl)-azetidin-2-one

(3S,4S)-3-Benzyloxy-4-[(S)-1-(tert-butyl-diphenyl-silanyloxy)-ethyl]-1-(4-methoxy-phenyl)-azetidin-2-one

(3R,4R)-3-Benzyloxy-4-[(S)-1-(tert-butyl-diphenyl-silanyloxy)-ethyl]-1-(4-methoxy-phenyl)-azetidin-2-one

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