1-Thio-α-D-mannose Natriumsalz

Base Information

• Chemical Name: 1-Thio-α-D-mannose Natriumsalz
• CAS No.: 111057-34-2
• Molecular Formula: C6H12 O5 S . Na
• Molecular Weight: 218.204
• Mol file: 111057-34-2.mol

Synonyms:a-D-Mannopyranose, 1-thio-,monosodium salt (9CI)

Chemical Property of 1-Thio-α-D-mannose Natriumsalz

Chemical Property:

• PSA: 90.15000
• LogP: -2.66680

Purity/Quality:

α-D-ThiomannoseSodiumSalt ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Thio-α-D-mannose Natriumsalz

There total 1 articles about 1-Thio-α-D-mannose Natriumsalz which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside (19879-84-6,50615-66-2,72541-16-3,72748-72-2,92691-83-3,110660-22-5,56981-51-2) → sodium salt of 1-thio-α-D-mannose (111057-34-2)

Guidance literature:

With sodium methylate; In methanol; at 20 ℃; for 0.5h;

DOI:10.1016/j.carres.2009.06.008

Reference yield: 81.0%

S-benzyl methanethiosulfonate (7559-62-8) + sodium salt of 1-thio-α-D-mannose (111057-34-2) → (α-D-mannopyranosyldithiomethylene)benzene (1189747-33-8)

Guidance literature:

In methanol; water; at 20 ℃;

DOI:10.1016/j.carres.2009.06.008

Reference yield: 79.0%

C10H14O4S4 (13329-29-8) + sodium salt of 1-thio-α-D-mannose (111057-34-2) → 1,2-bis(α-D-mannopyranosyldithiomethylene)benzene (1189747-27-0)

Guidance literature:

In methanol; water; at 20 ℃;

DOI:10.1016/j.carres.2009.06.008

upstream raw materials:

2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside

Downstream raw materials:

1,3-bis(α-D-mannopyranosyldithiomethylene)benzene

1,2-bis(α-D-mannopyranosyldithiomethylene)benzene

1,3,5-tris(α-D-mannopyranosyldithiomethylene)benzene

(α-D-mannopyranosyldithiomethylene)benzene

Refernces