(4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane

Base Information

Chemical Name:(4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane
CAS No.:1281922-72-2
Molecular Formula:C₂₆H₃₆O₆SSi
Molecular Weight:504.72
Hs Code.:

Synonyms:(4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane

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Chemical Property of (4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane

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Technology Process of (4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane

There total 5 articles about (4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1281922-85-7
C₂₆H₃₆O₅SSi

: 1281922-72-2
(4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane

Guidance literature:: With ruthenium trichloride; sodium periodate; In tetrachloromethane; water; acetonitrile; at 20 ℃; for 0.166667h;
DOI:10.1021/jo2001897

Reference yield:

: 303963-92-0
(3aR,6aR)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyl-3a,6a-dihydro-4H-cyclopenta[d][1,3]dioxol-4-one

: 1281922-72-2
(4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: palladium 10% on activated carbon; hydrogen / methanol / 20 °C

2: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 - 20 °C

3: dichloromethane; toluene / 48 h / 0 - 20 °C

4: thionyl chloride; triethylamine / dichloromethane / 0.17 h / 0 °C

5: sodium periodate; ruthenium trichloride / tetrachloromethane; water; acetonitrile / 0.17 h / 20 °C

With ruthenium trichloride; sodium tetrahydroborate; sodium periodate; thionyl chloride; cerium(III) chloride heptahydrate; palladium 10% on activated carbon; hydrogen; triethylamine; In methanol; tetrachloromethane; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/jo2001897

Reference yield:

: 1281922-74-4
6-(tert-butyldiphenylsilanyloxymethyl)-2,2-dimethyltetrahydrocyclopenta[1,3]dioxol-4-one

: 1281922-72-2
(4-tert-butoxy-2,2-dioxo-tetrahydro-2-yl-6-cyclopenta[1,3,2]-dioxathiol-5-ylmethoxy)-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 - 20 °C

2: dichloromethane; toluene / 48 h / 0 - 20 °C

3: thionyl chloride; triethylamine / dichloromethane / 0.17 h / 0 °C

4: sodium periodate; ruthenium trichloride / tetrachloromethane; water; acetonitrile / 0.17 h / 20 °C

With ruthenium trichloride; sodium tetrahydroborate; sodium periodate; thionyl chloride; cerium(III) chloride heptahydrate; triethylamine; In methanol; tetrachloromethane; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/jo2001897