RuCl(OAc)(PPh3)3

Base Information

• Chemical Name: RuCl(OAc)(PPh3)3
• CAS No.: 55978-89-7
• Molecular Formula: C₅₆H₄₈ClO₂P₃Ru
• Molecular Weight: 982.44
• Mol file: 55978-89-7.mol

Synonyms:Ru(OOCCH₃)Cl(P(C₆H₅)3)3

Chemical Property of RuCl(OAc)(PPh3)3

Chemical Property:

• Melting Point: 223-244°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chlorotris(triphenylphosphine)ruthenium(II) acetate 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36/37

MSDS Files:

Useful:

Technology Process of RuCl(OAc)(PPh3)3

There total 2 articles about RuCl(OAc)(PPh3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + sodium acetate trihydrate (6131-90-4) → RuCl(OAc)(PPh3)3 (55978-89-7)

Guidance literature:

In tert-butyl alcohol; Ru-complex and AcONa*3H2O were intimately ground together in a mortar and pestle in air, mixt. was exposed to vac. for 30 min, flask filled with Ar, t-BuOH added, solm. was refluxed with rapid stirring for 1 h; ppt. was isolated by filtration in air, washed successively with Et2O, water, MeOH, Et2O, dried under reduced pressure; elem. anal.;

DOI:10.1021/om00083a005

Reference yield: 82.0%

diruthenium(II,III) tetraacetatechloride → Ru(OOCCH3)Cl(P(C6H5)3)3 (55978-89-7)

Guidance literature:

With triphenylphosphine; In methanol; inert atmosphere (N2 or Ar), refluxing (1 h); partial solvent removal (vacuum), crystn. on cooling (-20°C, overnight), washing (methanol), drying (vacuum); elem. anal.;

DOI:10.1246/bcsj.61.2291

Reference yield: 93.0%

RuCl(OAc)(PPh3)3 (55978-89-7) + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → [RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)] (1003045-51-9)

Guidance literature:

In toluene; byproducts: PPh3; (N2); std. Schlenk technique; suspn. of Ru complex and ligand in toluenewas refluxed for 30 min; cooled to room temp.; filtered; washed (toluene, Et2O); elem. anal.;

DOI:10.1021/ic701773a

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

sodium acetate trihydrate

Downstream raw materials:

[RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)]