2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran

Base Information

Chemical Name:2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran
CAS No.:172587-77-8
Molecular Formula:C₂₃H₃₂O₄Si
Molecular Weight:400.59
Hs Code.:

Synonyms:2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran

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Chemical Property of 2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran

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Technology Process of 2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran

There total 7 articles about 2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 67-56-1
methanol

: 198192-49-3
(S)-3-(tert-Butyl-diphenyl-silanyloxy)-4-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-butyraldehyde

: 172587-77-8
2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran

Guidance literature:: With citric acid; Heating;
DOI:10.1021/ja972497r

Reference yield:

: 127793-60-6
(2R)-1-[(4S)-2,2-diethyl-[1,3]dioxolan-4-yl]-pent-4-en-2-ol

: 172587-77-8
2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / imidazole, 4-(dimethylamino)pyridine / dimethylformamide / Ambient temperature

2: 100 percent / ozone / CH₂Cl₂ / -78 °C

3: 62 percent / citric acid / Heating

With 1H-imidazole; dmap; ozone; citric acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja972497r

Reference yield:

: 198193-01-0
tert-Butyl-[(R)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-but-3-enyloxy]-diphenyl-silane

: 172587-77-8
2β-methoxy-4β-(diphenyl t-butylsiloxy)-6α-hydroxymethyl-tetrahydro-2H-pyran

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / ozone / CH₂Cl₂ / -78 °C

2: 62 percent / citric acid / Heating

With ozone; citric acid; In dichloromethane;
DOI:10.1021/ja972497r