meso-5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinatoplatinum

Base Information

• Chemical Name: meso-5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinatoplatinum
• CAS No.: 109781-47-7
• Molecular Formula: C44H8 F20 N4 Pt
• Molecular Weight: 1167.62
• European Community (EC) Number: 844-206-6
• Mol file: 109781-47-7.mol

Synonyms:5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrin;meso-Tetra(pentafluorophenyl)porphyrin;platinum(II) 5,10,15,20-tetrakis-(2,3,4,5,6-pentafluorophenyl)porphyrin;TFPP porphyrin

Chemical Property of meso-5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinatoplatinum

Chemical Property:

• PSA: 34.58000
• LogP: 9.21730
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 24
• Rotatable Bond Count: 4
• Exact Mass: 1167.007754
• Heavy Atom Count: 69
• Complexity: 1870

Purity/Quality:

98%,99%, ^*data from raw suppliers

Pt(II)meso-Tetra(pentafluorophenyl)porphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C3=NC(=C(C4=CC=C([N-]4)C(=C5C=CC(=N5)C(=C1[N-]2)C6=C(C(=C(C(=C6F)F)F)F)F)C7=C(C(=C(C(=C7F)F)F)F)F)C8=C(C(=C(C(=C8F)F)F)F)F)C=C3)C9=C(C(=C(C(=C9F)F)F)F)F.[Pt+2]
• Uses: Pt(II) meso-Tetra(pentafluorophenyl)porphine is a pressure-sensitive luminophore used in pressure-sensitive paints.

Technology Process of meso-5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinatoplatinum

There total 4 articles about meso-5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinatoplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

tetrakis(pentafluorophenyl)porphyrin (25440-14-6) → platinum(II)-5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrin (109781-47-7)

Guidance literature:

With bis(benzonitrile)dichloroplatinum(II); In benzonitrile; Inert atmosphere; Reflux;

DOI:10.1002/chem.201203774

Reference yield: 78.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + tetrakis(pentafluorophenyl)porphyrin (25440-14-6) → [5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrinato]platinum(II) (109781-47-7)

Guidance literature:

With sodium proprionate; In chlorobenzene; for 27h; under 760.051 Torr; Reflux;

DOI:10.1246/cl.141112

Reference yield:

→ [5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrinato]platinum(II) (109781-47-7)

Guidance literature:

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

tetrakis(pentafluorophenyl)porphyrin

platinum(II) chloride

Downstream raw materials:

platinum tetrakis(pentafluorophenyl)porpholactone

zinc(II) 5,10,15,20-tetrakis(pentafluorophenyl)porpholactone

Refernces

• 1、 Alemohammad, Tahereh,Safari, Nasser,Rayati, Saeed,Gheidi, Mahin,Mortazavimanesh, Anahita,Khavasi, Hamidreza. "Hydrogen bond controlled formation of trans-dihydroxo porphyrinato platinum(IV) complexes: Synthesis, characterization and catalytic activity in olefin epoxidation". . p. 198 - 208. Retrieved 2015/06/23.
• 2、 -. "NOVEL SUGAR-LINKED CHLORIN DERIVATIVE AND PROCESS FOR PRODUCTION THEREOF". Page/Page column 18. . Retrieved 2009/12/07.