(S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

Base Information

Chemical Name:(S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal
CAS No.:1589000-55-4
Molecular Formula:C₂₀H₃₃BrO₅Si
Molecular Weight:461.469
Hs Code.:

Synonyms:(S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

Suppliers and Price of (S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

Chemical Property:

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Technology Process of (S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

There total 7 articles about (S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1589000-86-1
(R)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propan-1-ol

: 1589000-55-4
(S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 16h;
DOI:10.1002/ejoc.201301363

Reference yield:

: 1589001-06-8
(S)-1-(triisopropylsilyloxy)-3-(4-methoxybenzyloxy)propan-2-ol

: 1589000-55-4
(S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

Guidance literature:: Multi-step reaction with 3 steps

1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 72 h / 0 - 20 °C / Inert atmosphere

2: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 1.5 h / 20 °C / Inert atmosphere

3: Dess-Martin periodane / dichloromethane / 16 h / 20 °C

With di-isopropyl azodicarboxylate; Dess-Martin periodane; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; water; 1: |Mitsunobu Displacement;
DOI:10.1002/ejoc.201301363

Reference yield:

: 1589000-84-9
(R)-{2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(4''-methoxybenzyloxy)propoxy}triisopropylsilane

: 1589000-55-4
(S)-2-[4'-bromo-2'-(methoxymethoxy)phenoxy]-3-(triisopropylsilyloxy)propanal

Guidance literature:: Multi-step reaction with 2 steps

1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 1.5 h / 20 °C / Inert atmosphere

2: Dess-Martin periodane / dichloromethane / 16 h / 20 °C

With Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1002/ejoc.201301363