phenyl(~2~H_2_)methyl

Base Information

• Chemical Name: phenyl(~2~H_2_)methyl
• CAS No.: 2154-54-3
• Molecular Formula: C7H5D2
• Molecular Weight: 93.1167
• Mol file: 2154-54-3.mol

Synonyms:Benzyl-a,a-d2 (7CI,8CI);Phenylmethyl-d2;

Chemical Property of phenyl(~2~H_2_)methyl

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phenyl(~2~H_2_)methyl

There total 14 articles about phenyl(~2~H_2_)methyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[1',1'-2H2]benzyl bromide (51271-29-5) → benzyl α-d2 radical (2154-54-3)

Guidance literature:

In gas; at 946.9 - 996.9 ℃; under 0.001 Torr;

DOI:10.1007/BF00699953

Reference yield:

benzoic acid ethyl ester (93-89-0,99341-95-4) → benzyl α-d2 radical (2154-54-3)

Guidance literature:

Multi-step reaction with 3 steps

1: LiAlD₄

2: HBr

3: gas / 946.9 - 996.9 °C / 0 Torr

With lithium aluminium deuteride; hydrogen bromide; In gas;

DOI:10.1007/BF00699953

Reference yield:

1,1-dideuteriophenylmethanol (21175-64-4) → benzyl α-d2 radical (2154-54-3)

Guidance literature:

Multi-step reaction with 2 steps

1: HBr

2: gas / 946.9 - 996.9 °C / 0 Torr

With hydrogen bromide; In gas;

DOI:10.1007/BF00699953

upstream raw materials:

3-methyl-butan-2-one

C₇H₅⁽²⁾H₃⁽¹⁺⁾

diethyl ether

tert-butyl methyl ether

Refernces

• 1、 Baskir, E. G.,Maltsev, A. K.,Korolev, V. A.,Khabashesku, V. N.,Nefedov, O. M.. "Generation and IR spectroscopic study of benzyl radical". . p. 1438 - 1440. Retrieved 2007/10/02.
• 2、 Kajii, Yoshizumi,Obi, Kinichi,Tanaka, Ikuzo,Ikeda, Noriaki,Nakashima, Nobuaki,Yoshihara, Keitaro. "Deuterium isotope effects on photodecomposition of alkylbenzenes". . p. 6115 - 6118. Retrieved 2007/10/02.