Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

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Chemical Name:Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester
CAS No.:88057-65-2
Molecular Formula:C₁₈H₃₅O₅P
Molecular Weight:362.447
Hs Code.:

Synonyms:Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

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Chemical Property of Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

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Technology Process of Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

There total 5 articles about Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 88057-82-3
Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester

: 88057-65-2
Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

Guidance literature:: With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 0 ℃; for 4h; Yield given;
DOI:10.1021/ja00315a044

Reference yield:

: 86509-55-9,86509-56-0,88154-78-3,88154-79-4
(R)-6-Butyl-5-methyl-cyclohex-2-enone

: 88057-65-2
Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: TiCl₄ / CH₂Cl₂ / 1.5 h / -78 °C

2: 1.) LDA, HMPT / 1.) THF, -78 deg C, 1.5h, 0 deg C, 20min; 2.) 23 deg C, 4h, THF

3: 9-BBN / tetrahydrofuran / 4 h / 0 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; 9-borabicyclo[3.3.1]nonane dimer; titanium tetrachloride; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00315a044

Reference yield:

: 88155-70-8
(2S,3R,5R)-5-Allyl-2-butyl-3-methyl-cyclohexanone

: 88057-65-2
Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LDA, HMPT / 1.) THF, -78 deg C, 1.5h, 0 deg C, 20min; 2.) 23 deg C, 4h, THF

2: 9-BBN / tetrahydrofuran / 4 h / 0 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; 9-borabicyclo[3.3.1]nonane dimer; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/ja00315a044