Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester

Base Information

• Chemical Name: Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester
• CAS No.: 88057-82-3
• Molecular Formula: C₁₈H₃₃O₄P
• Molecular Weight: 344.431

Synonyms:Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester

Chemical Property of Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester

Chemical Property:

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Technology Process of Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester

There total 2 articles about Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-6-Butyl-5-methyl-cyclohex-2-enone (86509-55-9,86509-56-0,88154-78-3,88154-79-4) → Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester (88057-82-3)

Guidance literature:

Multi-step reaction with 2 steps

1: TiCl₄ / CH₂Cl₂ / 1.5 h / -78 °C

2: 1.) LDA, HMPT / 1.) THF, -78 deg C, 1.5h, 0 deg C, 20min; 2.) 23 deg C, 4h, THF

With N,N,N,N,N,N-hexamethylphosphoric triamide; titanium tetrachloride; lithium diisopropyl amide; In dichloromethane;

DOI:10.1021/ja00315a044

Reference yield:

diethyl chlorophosphate (814-49-3) + (2S,3R,5R)-5-Allyl-2-butyl-3-methyl-cyclohexanone (88155-70-8) → Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester (88057-82-3)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; Yield given. Multistep reaction; 1.) THF, -78 deg C, 1.5h, 0 deg C, 20min; 2.) 23 deg C, 4h, THF;

DOI:10.1021/ja00315a044

Reference yield:

Phosphoric acid (3R,5R,6S)-3-allyl-6-butyl-5-methyl-cyclohex-1-enyl ester diethyl ester (88057-82-3) → Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester (88057-65-2)

Guidance literature:

With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 0 ℃; for 4h; Yield given;

DOI:10.1021/ja00315a044

upstream raw materials:

diethyl chlorophosphate

(2S,3R,5R)-5-Allyl-2-butyl-3-methyl-cyclohexanone

(R)-6-Butyl-5-methyl-cyclohex-2-enone

Downstream raw materials:

Phosphoric acid (3R,5R,6S)-6-butyl-3-(3-hydroxy-propyl)-5-methyl-cyclohex-1-enyl ester diethyl ester

3-((1R,4S,5R)-4-Butyl-5-methyl-cyclohex-2-enyl)-propan-1-ol

3-((1R,4S,5R)-4-Butyl-5-methyl-cyclohex-2-enyl)-propionaldehyde

(2aR,4aR,6R,7S,7aS,7bS)-2-Benzyl-7-butyl-6-methyl-decahydro-indeno[1,7-cd]isoxazole

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