Technology Process of (3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane
There total 1 articles about (3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
palladium diacetate; 1,1,3,3-tetramethylbutane isonitrile;
In
toluene;
Yield given. Yields of byproduct given;
Ambient temperature;
DOI:10.1021/ja00142a047
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 1.) RhCl(PPh3)2, catecholborane, 2.) H2O2, NaOAc
2: 86 percent / DMAP, Et3N / Ambient temperature
3: 1.) t-BuOK, 2.) H2O2, TBAF, KHCO3 / 1.) DMSO
4: 76 percent / imidazole
5: 93 percent / PPTS / acetone
6: 97 percent / TBAF / tetrahydrofuran / Ambient temperature
With
1H-imidazole; dmap; [RhCl(Ph3P)2]; potassium tert-butylate; tetrabutyl ammonium fluoride; dihydrogen peroxide; sodium acetate; pyridinium p-toluenesulfonate; potassium hydrogencarbonate; triethylamine; benzo[1,3,2]dioxaborole;
In
tetrahydrofuran; acetone;
DOI:10.1021/ja00142a047
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) RhCl(PPh3)2, catecholborane, 2.) H2O2, NaOAc
2: 86 percent / DMAP, Et3N / Ambient temperature
3: 1.) t-BuOK, 2.) H2O2, TBAF, KHCO3 / 1.) DMSO
4: 76 percent / imidazole
5: 93 percent / PPTS / acetone
With
1H-imidazole; dmap; [RhCl(Ph3P)2]; potassium tert-butylate; tetrabutyl ammonium fluoride; dihydrogen peroxide; sodium acetate; pyridinium p-toluenesulfonate; potassium hydrogencarbonate; triethylamine; benzo[1,3,2]dioxaborole;
In
acetone;
DOI:10.1021/ja00142a047
