(3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

Base Information

Chemical Name:(3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane
CAS No.:170238-50-3
Molecular Formula:C₃₀H₅₄OSi₂
Molecular Weight:486.929
Hs Code.:

Synonyms:(3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

Suppliers and Price of (3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

There total 1 articles about (3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₀H₅₄OSi₂

: 170238-50-3
(3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

: (3R,4S,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

Guidance literature:: With palladium diacetate; 1,1,3,3-tetramethylbutane isonitrile; In toluene; Yield given. Yields of byproduct given; Ambient temperature;
DOI:10.1021/ja00142a047

Reference yield:

: 170238-50-3
(3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

: [(4R,5R,6R)-2,2-Dimethyl-6-octyl-5-(2-trityloxy-ethyl)-[1,3]dioxan-4-yl]-methanol

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) RhCl(PPh₃)2, catecholborane, 2.) H₂O₂, NaOAc

2: 86 percent / DMAP, Et₃N / Ambient temperature

3: 1.) t-BuOK, 2.) H₂O₂, TBAF, KHCO₃ / 1.) DMSO

4: 76 percent / imidazole

5: 93 percent / PPTS / acetone

6: 97 percent / TBAF / tetrahydrofuran / Ambient temperature

With 1H-imidazole; dmap; [RhCl(Ph₃P)2]; potassium tert-butylate; tetrabutyl ammonium fluoride; dihydrogen peroxide; sodium acetate; pyridinium p-toluenesulfonate; potassium hydrogencarbonate; triethylamine; benzo[1,3,2]dioxaborole; In tetrahydrofuran; acetone;
DOI:10.1021/ja00142a047

Reference yield:

: 170238-50-3
(3R,4R,5R)-3-[(Dimethyl-phenyl-silanyl)-methyl]-2,2-diisobutyl-5-octyl-4-vinyl-[1,2]oxasilolane

: 170238-53-6
tert-Butyl-[(4R,5R,6R)-2,2-dimethyl-6-octyl-5-(2-trityloxy-ethyl)-[1,3]dioxan-4-ylmethoxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) RhCl(PPh₃)2, catecholborane, 2.) H₂O₂, NaOAc

2: 86 percent / DMAP, Et₃N / Ambient temperature

3: 1.) t-BuOK, 2.) H₂O₂, TBAF, KHCO₃ / 1.) DMSO

4: 76 percent / imidazole

5: 93 percent / PPTS / acetone

With 1H-imidazole; dmap; [RhCl(Ph₃P)2]; potassium tert-butylate; tetrabutyl ammonium fluoride; dihydrogen peroxide; sodium acetate; pyridinium p-toluenesulfonate; potassium hydrogencarbonate; triethylamine; benzo[1,3,2]dioxaborole; In acetone;
DOI:10.1021/ja00142a047