Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

Base Information

Chemical Name:Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I
CAS No.:122924-43-0
Molecular Formula:C₂₇H₂₄IOP₂Rh
Molecular Weight:656.244
Hs Code.:

Rh{(C<sub>6</sub>H<sub>5</sub>)2P(CH<sub>2</sub>)2P(C<sub>6</sub>H<sub>5</sub>)2}(CO)I

Synonyms:Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

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Technology Process of Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

There total 1 articles about Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: [Rh(CO)2(μ-I)]2

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 122924-43-0
Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

Guidance literature:: In toluene; using Schlenk techniques; to (Rh(CO)2I)2 dissolved in toluene added dropwise soln. of org. ligand in toluene; after 1 h ppt. filtered; washed (EtOH, ether); dried (air); soln. was recovered; concd.; left at -10°C for for 24 h to give a second crop; elem. anal.;
DOI:10.1021/ja0176191

Reference yield: 74.0%

: 122924-43-0
Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

: 67913-10-4
acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III)

Guidance literature:: With methyl iodide; In dichloromethane; under protective gas; Rh-complex dissolved in CH2Cl2; addn. of CH3I; reaction time 9h; reaction monitored by IR and NMR spectroscopies; analysis;
DOI:10.1021/om00114a025

Reference yield: 70.0%

: 122924-43-0
Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

: 74-88-4
methyl iodide

: 67913-10-4
acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III)

Guidance literature:: In dichloromethane; under N2 atm. using Schlenk techniques; Rh complex dissolved in CH2Cl2; excess MeI added; soln. stirred at room temp. for 3 h; soln. concd. (vac.); pptd. by addition of Et2O after cooling to -10°C for 24 h; elem. anal.;
DOI:10.1021/ja0176191