(2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate

Base Information

Chemical Name:(2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate
CAS No.:100582-51-2
Molecular Formula:C₂₆H₃₈O₅
Molecular Weight:430.585
Hs Code.:

Synonyms:(2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate

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Chemical Property of (2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate

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Technology Process of (2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate

There total 7 articles about (2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2468-55-5
5-iodopent-1-yne

: 100582-51-2
(2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) LDA, 2.) hexamethylphosphoramide / 1.) THF, -78 deg C, 1 h; 2.) THF, -78 deg C to room temperature, 15 h

2: 94 percent / lithium aluminium hydride / diethyl ether / 1.5 h / 0 °C

3: 85 percent / sodium hydride / dimethylformamide / 12 h / 0 - 20 °C

4: zirconiumbis(cyclopentadienyl) dichloride, n-Bu-Li

5: triethylamine / CH₂Cl₂ / 1 h / -5 °C

6: 15.84 g / sodium iodide / acetone / 15 h / Ambient temperature

7: 1.) THF, -78 deg C to room temp., 15 h; 2.) toluene, 3 h, reflux

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; n-butyllithium; zirconocene dichloride; sodium hydride; triethylamine; sodium iodide; lithium diisopropyl amide; In diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone;

Reference yield:

: 100582-49-8
2-methylhept-6-yn-1-ol

: 100582-51-2
(2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate

Guidance literature:: Multi-step reaction with 5 steps

1: 85 percent / sodium hydride / dimethylformamide / 12 h / 0 - 20 °C

2: zirconiumbis(cyclopentadienyl) dichloride, n-Bu-Li

3: triethylamine / CH₂Cl₂ / 1 h / -5 °C

4: 15.84 g / sodium iodide / acetone / 15 h / Ambient temperature

5: 1.) THF, -78 deg C to room temp., 15 h; 2.) toluene, 3 h, reflux

With n-butyllithium; zirconocene dichloride; sodium hydride; triethylamine; sodium iodide; In dichloromethane; N,N-dimethyl-formamide; acetone;

Reference yield:

: 100582-48-7
t-butyl 2-methylhept-6-ynoate

: 100582-51-2
(2E,6E)-ethyl 12-benzyloxy-3-ethoxycarbonyl-7,11-dimethyldodeca-2,6-dienoate

Guidance literature:: Multi-step reaction with 6 steps

1: 94 percent / lithium aluminium hydride / diethyl ether / 1.5 h / 0 °C

2: 85 percent / sodium hydride / dimethylformamide / 12 h / 0 - 20 °C

3: zirconiumbis(cyclopentadienyl) dichloride, n-Bu-Li

4: triethylamine / CH₂Cl₂ / 1 h / -5 °C

5: 15.84 g / sodium iodide / acetone / 15 h / Ambient temperature

6: 1.) THF, -78 deg C to room temp., 15 h; 2.) toluene, 3 h, reflux

With lithium aluminium tetrahydride; n-butyllithium; zirconocene dichloride; sodium hydride; triethylamine; sodium iodide; In diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone;