phenyl nonafluorobutyl selenide

Base Information

• Chemical Name: phenyl nonafluorobutyl selenide
• CAS No.: 133067-74-0
• Molecular Formula: C₁₀H₅F₉Se
• Molecular Weight: 375.095
• Mol file: 133067-74-0.mol

Synonyms:phenyl nonafluorobutyl selenide

Chemical Property of phenyl nonafluorobutyl selenide

Chemical Property:

Purity/Quality:

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Technology Process of phenyl nonafluorobutyl selenide

There total 7 articles about phenyl nonafluorobutyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane (423-39-2) + diphenyl diselenide (1666-13-3) → phenyl nonafluorobutyl selenide (133067-74-0)

Guidance literature:

With Tetrakis(dimethylamino)ethylen; In N,N-dimethyl-formamide; at 0 - 20 ℃;

DOI:10.1021/jo060250j

Reference yield:

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane (423-39-2) + n-Bu3SnSePh2 → phenyl nonafluorobutyl selenide (133067-74-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; cesium fluoride; In N,N-dimethyl-formamide; at 120 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2009.06.035

Reference yield:

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane (423-39-2) + sodium phenylselenide (23974-72-3) → phenyl nonafluorobutyl selenide (133067-74-0) + 1,1,1,2,2,3,3,4,4-nonafluoro-6-iodo-5-decene (158750-93-7) + (Z)-1-butyl-3,3,4,4,5,5,6,6,6-nonafluoro-1-hexenyl phenyl selenide + (E)-1-butyl-3,3,4,4,5,5,6,6,6-nonafluoro-1-hexenyl phenyl selenide

Guidance literature:

With hex-1-yne; In ethanol; for 2h; Yields of byproduct given; Ambient temperature;

DOI:10.1246/bcsj.67.2273

upstream raw materials:

1-hexene

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

diphenyl diselenide

isobutyl vinyl ether