(1,5,9-trimesityldipyrromethene)FeCl(pyridine)

Base Information

• Chemical Name: (1,5,9-trimesityldipyrromethene)FeCl(pyridine)
• CAS No.: 1114543-37-1
• Molecular Formula: C₄₁H₄₂ClFeN₃
• Molecular Weight: 668.105
• Mol file: 1114543-37-1.mol

Synonyms:(1,5,9-trimesityldipyrromethene)FeCl(pyridine)

Chemical Property of (1,5,9-trimesityldipyrromethene)FeCl(pyridine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,5,9-trimesityldipyrromethene)FeCl(pyridine)

There total 2 articles about (1,5,9-trimesityldipyrromethene)FeCl(pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

pyridine (110-86-1) + 1,5,9-trimesityldipyrromethene (1114543-34-8) + iron(II) chloride → (1,5,9-trimesityldipyrromethene)FeCl(pyridine) (1114543-37-1)

Guidance literature:

With LiN(Si(CH₃)3)2; In tetrahydrofuran; (CH3)3C6H2C(C4H2NC6H2(CH3)3)C4H3NC6H2(CH3)3 reacted under N2 with LiN(Si(CH3)3)2 in THF at 77 K to room temp., concd. (vac.), reacted with FeCl2in THF at 77 K to room temp. in the presence of C5H5N; evapd. (vac.), dissolved in hexane, filtered, evapd., washed;

DOI:10.1021/ic2009539

Reference yield:

pyridine (110-86-1) + (1,5,9-trimesityldipyrromethene)FeCl(THF) (1114543-36-0) → (1,5,9-trimesityldipyrromethene)FeCl(pyridine) (1114543-37-1)

Guidance literature:

In pyridine; Fe-complex reacted with pyridine;

DOI:10.1021/ic900219b

Reference yield:

1-Azidoadamantane (24886-73-5) + (1,5,9-trimesityldipyrromethene)FeCl(pyridine) (1114543-37-1) → (1,5,9-trimesityldipyrromethene)FeCl(NHAd) (1114543-38-2)

Guidance literature:

In neat (no solvent, solid phase); Fe-complex heated at 50°C for 7 d with ligand;

DOI:10.1021/ic900219b

upstream raw materials:

pyridine

(1,5,9-trimesityldipyrromethene)FeCl(THF)

1,5,9-trimesityldipyrromethene

Downstream raw materials:

(1,5,9-trimesityldipyrromethene)FeCl(NHAd)