((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

Base Information

Chemical Name:((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester
CAS No.:633302-56-4
Molecular Formula:C₃₄H₅₁NO₆Si
Molecular Weight:597.868
Hs Code.:

((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

Synonyms:((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

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Chemical Property of ((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

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Technology Process of ((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

There total 8 articles about ((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 633302-55-3
[(1Z,4Z)-6-(tert-Butyl-dimethyl-silanyloxy)-hexa-1,4-dienyl]-((2E,4E,10E)-(6S,7S,8R,9S)-7,9-dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

: 633302-56-4
((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: With pyridine; pyridine hydrogenfluoride; In tetrahydrofuran; at 0 ℃; for 5h;
DOI:10.1016/j.tet.2008.01.139

Reference yield:

: 633302-51-9
7-(tert-butyl-dimethyl-silanyloxy)-hepta-2,5-diyn-1-ol

: 633302-56-4
((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: hydrogen; ethylenediamine / P₂-Ni

2: Dess-Martin periodinane; 2,6-lutidine / 0 °C

3: NaClO₂; NaH₂PO₄

4: NaH; (PhO)2P(O)N₃ / 0 °C

5: 65 percent / toluene / 110 °C

6: 37 percent / sodium hexamethyldisilazide / tetrahydrofuran / -78 °C

7: 87 percent / HF*pyridine; pyridine

With pyridine; 2,6-dimethylpyridine; sodium chlorite; sodium dihydrogenphosphate; diphenyl phosphoryl azide; hydrogen; sodium hexamethyldisilazane; sodium hydride; Dess-Martin periodane; pyridine hydrogenfluoride; ethylenediamine; P₂-Ni; In tetrahydrofuran; toluene; 2: Dess-Martin oxidation / 5: Curtius rearrangement;
DOI:10.1071/CH03026

Reference yield:

: 633302-49-5
(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl chloride

: 633302-56-4
((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-hydroxy-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 37 percent / sodium hexamethyldisilazide / tetrahydrofuran / -78 °C

2: 87 percent / HF*pyridine; pyridine

With pyridine; sodium hexamethyldisilazane; pyridine hydrogenfluoride; In tetrahydrofuran;
DOI:10.1071/CH03026