Technology Process of C35H46O8Si
There total 23 articles about C35H46O8Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
(E)-4-(methoxymethoxy)-6-methyl-3-oxo-5-(prop-1-enyl)-1,3-dihydroisobenzofuran-1-carbonitrile;
With
lithium tert-butoxide;
In
tetrahydrofuran;
at -78 ℃;
for 0.0833333h;
6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-cyclohex-2-enone;
In
tetrahydrofuran;
at -78 - -22 ℃;
for 2.5h;
dimethyl sulfate;
In
tetrahydrofuran;
at -22 - 23 ℃;
for 4.5h;
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: sodium hydrogencarbonate; sodium hypochlorite / potassium bromide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / dichloromethane; water / 0.25 h / 23 °C
2.1: C13H18NO2(1-)*Li(1+) / toluene; hexane / 1.33 h / 0 °C / Inert atmosphere
2.2: 6 h / -70 - 10 °C
3.1: scandium tris(trifluoromethanesulfonate) / dichloromethane / 0.5 h / 23 °C
4.1: tetrahydrofuran / 2 h / 0 °C
5.1: Hoveyda-Grubbs catalyst second generation / benzene / 0.67 h / 23 °C / Inert atmosphere; Heating
6.1: lithium tert-butoxide / tetrahydrofuran / 0.08 h / -78 °C
6.2: 2.5 h / -78 - -22 °C
6.3: 4.5 h / -22 - 23 °C
With
C13H18NO2(1-)*Li(1+); sodium hypochlorite; sodium hydrogencarbonate; lithium tert-butoxide;
Hoveyda-Grubbs catalyst second generation; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium bromide; scandium tris(trifluoromethanesulfonate);
In
tetrahydrofuran; hexane; dichloromethane; water; toluene; benzene;
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: C13H18NO2(1-)*Li(1+) / toluene; hexane / 1.33 h / 0 °C / Inert atmosphere
1.2: 6 h / -70 - 10 °C
2.1: scandium tris(trifluoromethanesulfonate) / dichloromethane / 0.5 h / 23 °C
3.1: tetrahydrofuran / 2 h / 0 °C
4.1: Hoveyda-Grubbs catalyst second generation / benzene / 0.67 h / 23 °C / Inert atmosphere; Heating
5.1: lithium tert-butoxide / tetrahydrofuran / 0.08 h / -78 °C
5.2: 2.5 h / -78 - -22 °C
5.3: 4.5 h / -22 - 23 °C
With
C13H18NO2(1-)*Li(1+); lithium tert-butoxide;
Hoveyda-Grubbs catalyst second generation; scandium tris(trifluoromethanesulfonate);
In
tetrahydrofuran; hexane; dichloromethane; toluene; benzene;
