Technology Process of CHCH2CH2C6H3OCH3OSiC4H9(CH3)2CHOCHC6H3OCH3OSiC4H9(CH3)2Si(CH3)3
There total 10 articles about CHCH2CH2C6H3OCH3OSiC4H9(CH3)2CHOCHC6H3OCH3OSiC4H9(CH3)2Si(CH3)3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tetra-(n-butyl)ammonium iodide; zinc(II) iodide;
In
1,2-dichloro-ethane;
at 20 ℃;
for 1h;
DOI:10.1021/ol0164482
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: 78 percent / imidazole / dimethylformamide / 19 h / 20 °C
2.1: disiamylborane / diethyl ether / 3 h / 0 °C
2.2: 75 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / Heating
3.1: 84 percent / 20 h / 20 °C
4.1: LDA / diethyl ether; hexane / 5.5 h / 0 °C
4.2: 77 percent / diethyl ether; hexane / -120 - 20 °C
5.1: O3 / CH2Cl2 / 0.58 h / -78 °C
6.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / 20 °C
6.2: tetrahydrofuran; hexane / 19 h / 20 °C
7.1: n-Bu4NI; ZnI2 / 1,2-dichloro-ethane / 1 h / 20 °C
With
1H-imidazole; n-butyllithium; bis-(1,2-dimethylpropyl)borane; tetra-(n-butyl)ammonium iodide; ozone; zinc(II) iodide; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
6.1: Wittig reaction;
DOI:10.1021/ol0164482
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: 78 percent / imidazole / dimethylformamide / 19 h / 20 °C
2.1: disiamylborane / diethyl ether / 3 h / 0 °C
2.2: 75 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / Heating
3.1: 84 percent / 20 h / 20 °C
4.1: LDA / diethyl ether; hexane / 5.5 h / 0 °C
4.2: 77 percent / diethyl ether; hexane / -120 - 20 °C
5.1: O3 / CH2Cl2 / 0.58 h / -78 °C
6.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / 20 °C
6.2: tetrahydrofuran; hexane / 19 h / 20 °C
7.1: n-Bu4NI; ZnI2 / 1,2-dichloro-ethane / 1 h / 20 °C
With
1H-imidazole; n-butyllithium; bis-(1,2-dimethylpropyl)borane; tetra-(n-butyl)ammonium iodide; ozone; zinc(II) iodide; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
6.1: Wittig reaction;
DOI:10.1021/ol0164482
