Essigsaeure-<2-chlor-pentylester>

Base Information

• Chemical Name: Essigsaeure-<2-chlor-pentylester>
• CAS No.: 49633-67-2
• Molecular Formula: C₇H₁₃ClO₂
• Molecular Weight: 164.632
• Mol file: 49633-67-2.mol

Synonyms:Essigsaeure-<2-chlor-pentylester>

Chemical Property of Essigsaeure-<2-chlor-pentylester>

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Essigsaeure-<2-chlor-pentylester>

There total 2 articles about Essigsaeure-<2-chlor-pentylester> which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-pentyl acetate (628-63-7) → acetic acid-(3-chloro-pentyl ester) (49633-68-3) + 1-acetoxy-4-chloropentane (36978-15-1) + 5-chloropentyl acetate (20395-28-2) + Essigsaeure-<2-chlor-pentylester> (49633-67-2)

Guidance literature:

With N-chloropiperidine; 2,2'-azobis(isobutyronitrile); In trifluoroacetic acid; at 30 ℃; Product distribution; Rate constant; Irradiation; relative rate constants, position selectivity, substrate selectivity;

Reference yield:

1-pentyl acetate (628-63-7) → acetic acid-(3-chloro-pentyl ester) (49633-68-3) + 1-acetoxy-4-chloropentane (36978-15-1) + 5-chloropentyl acetate (20395-28-2) + Essigsaeure-(α-chlor-pentylester) (13398-06-6) + Essigsaeure-<2-chlor-pentylester> (49633-67-2)

Guidance literature:

With chlorine; In neat (no solvent); Product distribution; Ambient temperature; chlorine substitution on the alcoholic chain of aliphatic C₂-C₈ n-alkyl acetates, chloroacetates, dichloroacetates and trichloroacetates; formation of monochloro isomers;

upstream raw materials:

1-pentyl acetate

Refernces

• 1、 Dneprovskii, A. S.,Mil'tsov, S. A.,Arbuzov, P. V.. "MECHANISMS OF FREE-RADICAL REACTIONS. XXIV. QUANTITATIVE DESCRIPTION OF THE POLAR EFFECTS OF SUBSTITUENTS ON THE KINETICS OF THE FREE-RADICAL CHLORINATION OF ALIPHATIC COMPOUNDS BY N-CHLOROPIPERIDINE". . p. 1826 - 1835. Retrieved 2007/10/02.
• 2、 Kophornen, Ilpo O. O.. "Chlorination of Carboxylic Acid Derivatives. X. Chlorine Substitution on the Alcohol Chain of Aliphatic C2-C8 Alkyl Chloro-, Dichloro- and Trichloroacetates". . p. 721 - 724. Retrieved 2007/10/02.