(dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

Base Information

Chemical Name:(dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate
CAS No.:1051942-93-8
Molecular Formula:C₂₆H₃₁NO₂Si
Molecular Weight:419.607
Hs Code.:

(dimethylphenylsilyl)-[1,1-2H<sub>2</sub>]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

Synonyms:(dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

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Technology Process of (dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

There total 10 articles about (dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 869218-44-0
(dimethylphenylsilyl)methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

: 1051942-93-8
(dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

Guidance literature:: (dimethylphenylsilyl)methyl (S,S)-N,N-bis(1-phenylethyl)carbamate; With N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium; In tetrahydrofuran; cyclohexane; at -78 ℃; for 0.166667h;

With water-d2; In tetrahydrofuran; cyclohexane; at -78 ℃; for 15h;
DOI:10.1021/ja051568g

Reference yield:

: 17881-97-9
(hydroxymethyl)dimethylphenylsilane

: 1051942-93-8
(dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 4.92 g / DMAP / toluene / Heating

2.1: s-BuLi; TMEDA / tetrahydrofuran; cyclohexane / 0.17 h / -78 °C

2.2: 92 percent / D₂O / tetrahydrofuran; cyclohexane / 15 h / -78 °C

With dmap; N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium; In tetrahydrofuran; cyclohexane; toluene;
DOI:10.1021/ja051568g

Reference yield:

: 1833-51-8
chloromethyldimethylphenylsilane

: 1051942-93-8
(dimethylphenylsilyl)-[1,1-2H₂]methyl (S,S)-N,N-bis(1-phenylethyl)carbamate

Guidance literature:: Multi-step reaction with 4 steps

1.1: NaI / dimethylformamide / 2 h / Heating

2.1: 21.68 g / LiAlH₄ / diethyl ether / 1 h / Heating

3.1: 4.92 g / DMAP / toluene / Heating

4.1: s-BuLi; TMEDA / tetrahydrofuran; cyclohexane / 0.17 h / -78 °C

4.2: 92 percent / D₂O / tetrahydrofuran; cyclohexane / 15 h / -78 °C

With dmap; lithium aluminium tetrahydride; N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium; sodium iodide; In tetrahydrofuran; diethyl ether; cyclohexane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja051568g