2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

Base Information

Chemical Name:2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate
CAS No.:1159795-87-5
Molecular Formula:C₁₈H₂₉BrO₅Si
Molecular Weight:433.415
Hs Code.:

Synonyms:2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

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Chemical Property of 2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

Chemical Property:

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Technology Process of 2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

There total 1 articles about 2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: trimethyl(2-((tributylstannyl)methoxy)ethyl)silane

: 680997-58-4
carbonic acid 2-bromo-3-tert-butoxycarbonyloxy-6-formyl-phenyl ester tert-butyl ester

: 1159795-87-5
2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

Guidance literature:: trimethyl(2-((tributylstannyl)methoxy)ethyl)silane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

carbonic acid 2-bromo-3-tert-butoxycarbonyloxy-6-formyl-phenyl ester tert-butyl ester; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Further stages; Inert atmosphere;
DOI:10.1021/jo900401k

Reference yield: 87.0%

: 1159795-87-5
2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

: 207680-77-1
(R)-2-hydroxy-N-methoxy-N-methylpropanamide

: 1159795-88-6
(S)-2-bromo-3-(1-(methoxy(methyl)amino)-1-oxopropan-2-yloxy)-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 ℃; for 24h; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/jo900401k

Reference yield:

: 1159795-87-5
2-bromo-3-hydroxy-4-(2-(2-(trimethylsilyl)ethoxy)ethyl)phenyl tert-butyl carbonate

: 177905-46-3
(S)-2-hydroxy-N-methoxy-N-methyl-propionamide

: C₂₃H₃₈BrNO₇Si

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.tet.2010.05.041