β-styryl-N-pyrrolidinylmethyldimethylsilane

Base Information

• Chemical Name: β-styryl-N-pyrrolidinylmethyldimethylsilane
• CAS No.: 119873-73-3
• Molecular Formula: C₁₅H₂₃NSi
• Molecular Weight: 245.44
• Mol file: 119873-73-3.mol

Synonyms:β-styryl-N-pyrrolidinylmethyldimethylsilane

Chemical Property of β-styryl-N-pyrrolidinylmethyldimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of β-styryl-N-pyrrolidinylmethyldimethylsilane

There total 4 articles about β-styryl-N-pyrrolidinylmethyldimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

pyrrolidine (123-75-1) + β-styrylchloromethyldimethylsilane (104891-66-9) → β-styryl-N-pyrrolidinylmethyldimethylsilane (119873-73-3)

Guidance literature:

at 80 ℃; for 20h;

DOI:10.1039/c39880001280

Reference yield:

[(E)-2-bromoethenyl]benzene (588-72-7,1340-14-3) → β-styryl-N-pyrrolidinylmethyldimethylsilane (119873-73-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) tert-butyllithium / 1.) ether, pentane, -25 deg C, 2 h, 2.) -> room temperature, overnight

2: 73 percent / 20 h / 80 °C

With tert.-butyl lithium;

Reference yield:

(E)-2-phenylethenyllithium (4843-72-5,6160-69-6,62839-69-4) → β-styryl-N-pyrrolidinylmethyldimethylsilane (119873-73-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / diethyl ether / -25 °C

2: 73 percent / 20 h / 80 °C

In diethyl ether;

DOI:10.1039/c39880001280

upstream raw materials:

pyrrolidine

β-styrylchloromethyldimethylsilane

(E)-2-phenylethenyllithium

[(E)-2-bromoethenyl]benzene

Downstream raw materials:

(S)-styrene oxide

Dimethyl-(3-phenyl-oxiranyl)-silanol

trans,trans-1,4-Diphenyl-1,3-butadiene

(R)-Styrene oxide