104891-66-9Relevant academic research and scientific papers
Enantioselective synthesis of epoxides via Sharpless epoxidation of alkenylsilanols
Chan, T. H.,Chen, L. M.,Wang, D.,Li, L. H.
, p. 60 - 67 (2007/10/02)
Enantioselective synthesis of simple epoxides can be achieved by Sharpless epoxidation of alkenylsilanols followed by protodesilylation of the chiral epoxysilanols.The approach has been applied to the synthesis of frontalin.
Enantioselective Synthesis of Epoxides: Sharpless Epoxidation of Alkenysilanols
Chan, T. H.,Chen, L. M.,Wang, D.
, p. 1280 - 1281 (2007/10/02)
Sharpless epoxidation of the alkenylsilanol (6) followed by protodesilylation gave styrene oxide with high enentiomeric excess.
STEREOSELECTIVE SYNTHESIS OF ALLYLSILANES FROM CHLOROMETHYLSILYLALKYNES
Shiragami, Hiroshi,Kawamoto, Takuo,Utimoto, Kiitiro,Nozaki, Hitosi
, p. 589 - 592 (2007/10/02)
Regio- and stereoselective hydralumination of 1-chloromethyldimethylsilyl-1-alkyne with DIBAH affords (Z)-1-chloromethyldimethylsilyl-1-diisobutylalumino-1-alkene which gives (E)-1-trimethylsilyl-2-alkene as a sole product by successive treatment with 3 e
