(1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde

Base Information

Chemical Name:(1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde
CAS No.:864079-41-4
Molecular Formula:C₁₆H₃₀O₂Si
Molecular Weight:282.498
Hs Code.:

Synonyms:(1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde

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Chemical Property of (1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde

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Technology Process of (1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde

There total 6 articles about (1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 864079-39-0
[(1R,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl]-methanol

: 864079-41-4
(1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde

Guidance literature:: With dipyridinium dichromate;
DOI:10.1055/s-2005-871555

Reference yield:

: 864079-37-8
(1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarboxylic acid ethyl ester

: 864079-41-4
(1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / DIBAL-H / toluene / 3 h / -78 °C

2: 57 percent / PDC

With dipyridinium dichromate; diisobutylaluminium hydride; In toluene;
DOI:10.1055/s-2005-871555

Reference yield:

: 61586-78-5
ethyl (1R,2S)-2-hydroxycyclohexane-1-carboxylate

: 864079-41-4
(1S,2S)-1-Allyl-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: LDA / tetrahydrofuran / 0.5 h / -60 - -15 °C

1.2: 90 percent / tetrahydrofuran / 4.5 h / -15 - 20 °C

2.1: 82 percent / DIBAL-H / toluene / 3 h / -78 °C

3.1: 57 percent / PDC

With dipyridinium dichromate; diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; toluene;
DOI:10.1055/s-2005-871555