5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan

Base Information

Chemical Name:5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan
CAS No.:944382-67-6
Molecular Formula:C₂₇H₃₄O₃Si
Molecular Weight:434.651
Hs Code.:

Synonyms:5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan

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Chemical Property of 5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan

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Technology Process of 5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan

There total 4 articles about 5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1027994-01-9
C₃₃H₄₈O₃Si₂

: 944382-67-6
5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan

Guidance literature:: With pyridinium p-toluenesulfonate; In methanol; at 20 ℃; for 24h;
DOI:10.1039/b703373g

Reference yield:

: 26908-23-6
3-furan-2-yl-propan-1-ol

: 944382-67-6
5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan

Guidance literature:: Multi-step reaction with 3 steps

1.1: 97 percent / 4-dimethylaminopyridine; triethylamine / CH₂Cl₂ / 0 - 20 °C

2.1: t-butyllithium / pentane; tetrahydrofuran / 3 h / -78 - -20 °C

2.2: tributyltin chloride / pentane; tetrahydrofuran / 3 h / -20 - 20 °C

2.3: (bis)-triphenylphosphine palladium(II) chloride / pentane; tetrahydrofuran / 16 h / Heating

3.1: 0.21 g / pyridinium p-toluenesulphonate / methanol / 24 h / 20 °C

With dmap; tert.-butyl lithium; pyridinium p-toluenesulfonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; pentane; 2.3: Stille coupling reaction;
DOI:10.1039/b703373g

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 944382-67-6
5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan

Guidance literature:: Multi-step reaction with 3 steps

1.1: 97 percent / 4-dimethylaminopyridine; triethylamine / CH₂Cl₂ / 0 - 20 °C

2.1: t-butyllithium / pentane; tetrahydrofuran / 3 h / -78 - -20 °C

2.2: tributyltin chloride / pentane; tetrahydrofuran / 3 h / -20 - 20 °C

2.3: (bis)-triphenylphosphine palladium(II) chloride / pentane; tetrahydrofuran / 16 h / Heating

3.1: 0.21 g / pyridinium p-toluenesulphonate / methanol / 24 h / 20 °C

With dmap; tert.-butyl lithium; pyridinium p-toluenesulfonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; pentane; 2.3: Stille coupling reaction;
DOI:10.1039/b703373g