1027994-01-9

Upstream product

• 89922-82-7 3-(tert-butyldimethylsilanyloxy)propionaldehyde 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 73842-99-6 3-tert-butyldimethylsilyloxy-1-propanol 
• 26908-23-6 3-furan-2-yl-propan-1-ol 
• 108330-00-3 (E)-4-<(tert-butyldimethylsilyl)oxy>-1-iodo-1-butene 
• 738604-46-1 2-(tert-butyldiphenylsilyloxy-propan-1'-yl)-furan 

Downstream Products

• 944382-67-6 5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-but-1'-en-1'-yl)-furan 
• 944382-53-0 2-(4'-acetoxy-butan-1'-yl)-5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-furan 
• 944382-52-9 5-(3'-tert-butyldiphenylsilyloxy-propan-1'-yl)-2-(4-hydroxy-butan-1'-yl)-furan 

Relevant academic research and scientific papers

Cascade radical-mediated cyclisations with conjugated ynone electrophores. An approach to the synthesis of steroids and other novel ring-fused polycyclic carbocycles

A cascade radical-mediated Diels-Alder reaction with the iododienynone 16b produced the tricyclic ketone 17 (22%). By contrast, treatment of the substituted furans 36 and 47 with Bu3SnH-AIBN, instead led to the tetracycles 44 and 58 respectivel