3-(4-Methoxyphenyl)-6-hydroxyphthalic acid dimethyl ester

Base Information

Chemical Name:3-(4-Methoxyphenyl)-6-hydroxyphthalic acid dimethyl ester
CAS No.:17113-34-7
Molecular Formula:C₁₇H₁₆O₆
Molecular Weight:316.31
Hs Code.:
DSSTox Substance ID:DTXSID901163727
Nikkaji Number:J873.286H

Synonyms:17113-34-7;CBMicro_042211;Oprea1_774476;DTXSID901163727;STL523223;AKOS030500089;BIM-0041971.P001;EU-0077906;SR-01000490065;SR-01000490065-1;dimethyl 4-hydroxy-4'-methoxybiphenyl-2,3-dicarboxylate;3-(4-Methoxyphenyl)-6-hydroxyphthalic acid dimethyl ester;2,3-Dimethyl 4-hydroxy-4'-methoxy[1,1'-biphenyl]-2,3-dicarboxylate

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Chemical Property of 3-(4-Methoxyphenyl)-6-hydroxyphthalic acid dimethyl ester

Chemical Property:

XLogP3:3.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:6
Exact Mass:316.09468823
Heavy Atom Count:23
Complexity:415

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=CC=C(C=C1)C2=C(C(=C(C=C2)O)C(=O)OC)C(=O)OC

Technology Process of 3-(4-Methoxyphenyl)-6-hydroxyphthalic acid dimethyl ester

There total 2 articles about 3-(4-Methoxyphenyl)-6-hydroxyphthalic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17113-31-4
2-(4-methoxyphenyl)furan

: 762-42-5
dimethyl acetylenedicarboxylate

: C₁₇H₁₆O₆

: 17113-34-7
dimethyl 3-hydroxy-6-(4-methoxyphenyl)phthalate

Guidance literature:: With iridium(III) chloride trihydrate; In toluene; at 70 ℃; for 48h; Air atmosphere;
DOI:10.1016/j.tetlet.2011.09.068

Reference yield:

: 17113-31-4
2-(4-methoxyphenyl)furan

: 762-42-5
dimethyl acetylenedicarboxylate

: 17113-34-7
dimethyl 3-hydroxy-6-(4-methoxyphenyl)phthalate

: 20842-13-1
1-(4-Methoxy-phenyl)-7-oxa-bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylic acid dimethyl ester

Guidance literature:: zinc(II) iodide; In dichloromethane;
DOI:10.1080/10587250008023846

Reference yield:

: 17113-34-7
dimethyl 3-hydroxy-6-(4-methoxyphenyl)phthalate

: dimethyl 2,2-dimethyl-6-(4-methoxyphenyl)-2H-chromene-7,8-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 58 percent / K₂CO₃; KI; CuI / dimethylformamide / 2 h / 65 °C

2: 50 percent / dimethylformamide; N,N-dimethyl-aniline / 140 - 150 °C

With copper(l) iodide; potassium carbonate; potassium iodide; In N,N-dimethyl-aniline; N,N-dimethyl-formamide;
DOI:10.1080/10587250008023846