[(C₅H₄Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C₆F₅)4]

Base Information

• Chemical Name: [(C₅H₄Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C₆F₅)4]
• CAS No.: 900534-74-9
• Molecular Formula: C₂₂H₃₅O₂Zr*C₂₄BF₂₀
• Molecular Weight: 1101.79
• Mol file: 900534-74-9.mol

Synonyms:[(C₅H₄Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C₆F₅)4]

Chemical Property of [(C₅H₄Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C₆F₅)4]

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [(C₅H₄Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C₆F₅)4]

There total 1 articles about [(C₅H₄Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C₆F₅)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloromethane-d2 (1665-00-5) + tert-butyl vinyl ether (926-02-3) + [(C5H4Me)2Zr(O(t)Bu)][B(C6F5)4] (512163-89-2) → [(C5H4Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C6F5)4] (900534-74-9)

Guidance literature:

In dichloromethane-d2; (N2); addn. of CD2Cl2 to zirconium complex at -78°C, shaking, cooling to -196°C, addn. of excess alkene, warming to -78°C; not isolated, detected by NMR;

DOI:10.1021/ja0575225

Reference yield:

[(C5H4Me)2Zr(O(t)Bu)(tert-butyl vinyl ether)][B(C6F5)4] (900534-74-9) + trimethylphosphane (594-09-2) → [(C5H4Me)2Zr(O(t)Bu)(PMe3)][B(C6F5)4]

Guidance literature:

In not given; byproducts: tert-butyl vinyl ether;

DOI:10.1021/ja0575225

upstream raw materials:

dichloromethane-d2

tert-butyl vinyl ether

[(C₅H₄Me)2Zr(O(t)Bu)][B(C₆F₅)4]