[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

Base Information

Chemical Name:[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]
CAS No.:137436-45-4
Molecular Formula:C₂₄H₂₀B*C₄₄H₄₇FeP₄
Molecular Weight:1074.83
Hs Code.:

Synonyms:[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

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Chemical Property of [(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

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Technology Process of [(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

There total 3 articles about [(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 128973-37-5
[FeH₂(P(CH₂CH₂P(C₆H₅)2)3)]

: 74-85-1
ethene

: 143-66-8
sodium tetraphenyl borate

: 137436-45-4
[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

Guidance literature:: With CF₃SO₂OCH₃; In tetrahydrofuran; absence of air and moisture; addn. of MeOTf to Fe-complex (in THF), stirring under C2H4 for 1 h, addn. of NaBPh4; addn. of EtOH (satd. with C2H4), crystn. on slow concn. (C2H4-stream);
DOI:10.1021/ic960736q

Reference yield: 79.0%

: 54477-71-3
{(P(CH₂CH₂P(C₆H₅)2)3)Fe(H)(N₂)}⁽¹⁺⁾*B(C₆H₅)4^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)Fe(H)(N₂)}B(C₆H₅)4

: 74-85-1
ethene

: 137436-45-4
[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

Guidance literature:: In tetrahydrofuran; byproducts: N2; bubbling C2H4 through a stirred THF soln. of the dinitrogen complex salt (20 min), addn. of ethanol; slow evapn. of solvent, crystn., washing (ethanol, petroleum ether), drying (under Ar); elem. anal.;

Reference yield: 76.0%

: 54477-71-3
[(P(CH2CH2PPh2)3)Fe(H)(η(1)-N2)][BPh4]

: 74-85-1
ethene

: 137436-45-4
[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

Guidance literature:: In tetrahydrofuran; absence of air and moisture; bubbling C2H4 at 0°C for 4 h; addn. of EtOH, crystn. on slow concn. (C2H4-stream); elem. anal.;
DOI:10.1021/ic960736q