{(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}{B(C₆H₅)4}

Base Information

• Chemical Name: {(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}{B(C₆H₅)4}
• CAS No.: 54477-71-3
• Molecular Formula: C₂₄H₂₀B*C₄₂H₄₃FeN₂P₄
• Molecular Weight: 1074.79
• Mol file: 54477-71-3.mol

Synonyms:{(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}{B(C₆H₅)4}

Chemical Property of {(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}{B(C₆H₅)4}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}{B(C₆H₅)4}

There total 2 articles about {(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}{B(C₆H₅)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4] (137436-45-4) + nitrogen (7727-37-9) → [(P(CH2CH2PPh2)3)Fe(H)(η(1)-N2)][BPh4] (54477-71-3)

Guidance literature:

In not given; byproducts: C2H4; absence of air and moisture;

DOI:10.1021/ic960736q

Reference yield:

[(P(CH2CH2PPh2)3)Fe(H)(η(2)-H2)][BPh4] (123122-81-6) → (P(CH2CH2P(C6H5)2)3)Fe(H)(CO)(1+)*B(C6H5)4(1-)={(P(CH2CH2P(C6H5)2)3)Fe(H)(CO)}B(C6H5)4 (54477-77-9) + {(PP3)FeH(N2)}BPh4 (54477-71-3)

Guidance literature:

With nitrogen; 1-Phenylbut-1-en-3-one; In 1,4-dioxane; inert atmosphere; in dioxane/cyclopentanol (10:3 v/v), stirring (80°C, 2 h), cooling to 0°C, bubbling N2; not isolated, detd. by (31)P-NMR spectroscopy;

Reference yield: 92.0%

[(P(CH2CH2PPh2)3)Fe(H)(η(1)-N2)][BPh4] (54477-71-3) + carbon monoxide (201230-82-2) → FeH(CO)(P(CH2CH2P(C6H5)2)3)(1+)*B(C6H5)4(1-)=[FeH(CO)(P(CH2CH2P(C6H5)2)3)][B(C6H5)4] (54477-77-9)

Guidance literature:

In tetrahydrofuran; absence of air and moisture; bubbling CO at 0°C for 4 h; addn. of EtOH, crystn. on slow concn. (CO-stream); elem. anal.;

DOI:10.1021/ic960736q

upstream raw materials:

[(P(CH2CH2PPh2)3)Fe(H)(η(2)-H2)][BPh4]

[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

nitrogen

Downstream raw materials:

1-penten

1-cis-Methoxy-1,3-trans-butadiene

styrene

[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]