1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

Base Information

Chemical Name:1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol
CAS No.:132628-30-9
Molecular Formula:C₁₉H₂₆O₆
Molecular Weight:350.412
Hs Code.:

Synonyms:1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

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Chemical Property of 1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

Chemical Property:

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Technology Process of 1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

There total 1 articles about 1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 132628-27-4
4-O-(Phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

: 77-76-9
2,2-dimethoxy-propane

: 132628-29-6
2,3-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

: 132628-30-9
1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

Guidance literature:: With toluene-4-sulfonic acid; In tetrahydrofuran; for 1.66667h;
DOI:10.1016/0040-4020(91)80004-L

Reference yield: 96.0%

: 100-39-0
benzyl bromide

: 132628-30-9
1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

: 131147-11-0,132697-47-3
(±)-2,3-O-isopropylidene-1,5,6-tri-O-benzyl-4-O-allyl-myo-inositol

Guidance literature:: With 18-crown-6 ether; potassium tert-butylate; In tetrahydrofuran; for 1h;
DOI:10.1016/0040-4020(91)80004-L

Reference yield:

: 132628-30-9
1,2-O-(1-Methylethylidene)-4-O-(phenylmethyl)-6-O-(2-propenyl)-D,L-myo-inositol

: Phosphoric acid mono-[(1R,2R,3S,4R,5R,6R)-2-(2-amino-ethoxy)-3,4,5,6-tetrahydroxy-cyclohexyl] ester

Guidance literature:: Multi-step reaction with 9 steps

1: 96 percent / potassium tert-butoxide, 18-crown-6 / tetrahydrofuran / 1 h

2: OsO₄, N-methylmorpholine-N-oxide / acetone; H₂O

3: NaIO₄ / dioxane; H₂O / 25 h

4: NaBH₄ / tetrahydrofuran; propan-2-ol / 1 h / 0 deg C to room temperature

5: 100 percent / pyridine / CH₂Cl₂ / 1.) 0 deg C, 30 min, 2.) room temperature, 1 h

6: 98 percent / NaN₃ / dimethylsulfoxide / 1.83 h / 60 °C

7: 100 percent / 0.5 M aq. HCl / methanol / 1.17 h / Heating

8: 1.) methyl dichlorophosphate, pyridine, 2.) 2.0 M HCl / 1.) 80 min, 2.) water (pH 1)

9: hydrogen, NaHCO₃ / 10 percent Pd-C / H₂O; tetrahydrofuran; ethanol / 42 h / 2585.7 Torr

With pyridine; hydrogenchloride; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; sodium azide; 18-crown-6 ether; potassium tert-butylate; hydrogen; sodium hydrogencarbonate; 4-methylmorpholine N-oxide; methyl dichlorophosphoridate; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; methanol; ethanol; dichloromethane; water; dimethyl sulfoxide; isopropyl alcohol; acetone;
DOI:10.1016/0040-4020(91)80004-L