(η5-C5Me5)(PMe3)2Ru(NPh2)

Base Information

Chemical Name:(η5-C5Me5)(PMe3)2Ru(NPh2)
CAS No.:106734-56-9
Molecular Formula:C₂₈H₄₃NP₂Ru
Molecular Weight:556.674
Hs Code.:

Synonyms:(η5-C5Me5)(PMe3)2Ru(NPh2)

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Chemical Property of (η5-C5Me5)(PMe3)2Ru(NPh2)

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Technology Process of (η5-C5Me5)(PMe3)2Ru(NPh2)

There total 3 articles about (η5-C5Me5)(PMe3)2Ru(NPh2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: [(pentamethylcyclopentadienyl)RuCl(PMe₃)2]

: 5856-89-3
lithium diphenylamide

: 106734-56-9
(η5-C5Me5)(PMe3)2Ru(NPh2)

Guidance literature:: In tetrahydrofuran; react. in a vac. dry box; addn. of THF to a mixture of Ru-complex and LiNPh2 at -78°C, warming to room temp., stirring for 12 h; evapn., drying of residue, extn. with benzene, filtration, evai180 slurrying of powder in Et2O, filtration (cold frit), washing 3 times with Et2O, recrystn. from THF; elem. anal.;
DOI:10.1021/ja00239a026

Reference yield:

: (η5-C5Me5)Ru(PMe3)2(OH)

: 106734-56-9
(η5-C5Me5)(PMe3)2Ru(NPh2)

Guidance literature:: With CO; In tetrahydrofuran; byproducts: (C5(CH3)5)(P(CH3)3)2Ru(CO)H, (C5(CH3)5)(P(CH3)3)2RuCOOH; heating (25°C) of Ru-complex with CO in THF (vac. dry box);
DOI:10.1021/ja00239a026